Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence. (Q42156714)

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2 March 2020

title

Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence (English)

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2 March 2020

Xiao-Na Wang

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2 March 2020

Gabrielle N Winston-McPherson

series ordinal

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2 March 2020

Mary C Walton

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2 March 2020

Kyle A DeKorver

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2 March 2020

language of work or name

English

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publication date

10 June 2013

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Journal of Organic Chemistry

2 March 2020

published in

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volume

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issue

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2 March 2020

page(s)

6233-6244

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The hexadehydro-Diels-Alder reaction

2 March 2020

cites work

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An intramolecular [2 + 2] cycloaddition of ketenimines via palladium-catalyzed rearrangements of N-allyl-ynamides

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Carbocyclization cascades of allyl ketenimines via aza-Claisen rearrangements of N-phosphoryl-N-allyl-ynamides

29 May 2018

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Introducing a New Class of N-Phosphoryl Ynamides via Cu(I)-Catalyzed Amidations of Alkynyl Bromides

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N-Allyl-N-sulfonyl Ynamides as Synthetic Precursors to Amidines and Vinylogous Amidines. An Unexpected N-to-C 1,3-Sulfonyl Shift in Nitrile Synthesis

29 May 2018

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Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones

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29 May 2018

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An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides

29 May 2018

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29 May 2018

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Ynamides: versatile tools in organic synthesis

29 May 2018

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A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides

29 May 2018

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Synthesis of alkynyl ethers and low-temperature sigmatropic rearrangement of allyl and benzyl alkynyl ethers

29 May 2018

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Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis

29 May 2018

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Synthesis of enamines, enol ethers and related compounds by cross-coupling reactions

29 May 2018

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Claisen rearrangement over the past nine decades

29 May 2018

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Alkane C–H Insertion by Aryne Intermediates with a Silver Catalyst

29 May 2018

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Intramolecular carbolithiation of N-allyl-ynamides: an efficient entry to 1,4-dihydropyridines and pyridines - application to a formal synthesis of sarizotan

17 August 2018

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Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex

17 August 2018

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Synthetic studies in the intramolecular carbocyclization of N-acyloxyiminium ions. Stereoelectronic and steric implications of nucleophilic alkene, alkyne, and allene tethers

17 August 2018

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17 August 2018

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Formal intermolecular 4 + 4 approach to cyclooctanoids: 4 + 3 capture of the Nazarov oxyallyl intermediate with simple 1,3-dienes.

17 August 2018

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17 August 2018

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1 December 2018

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1 December 2018

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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12 December 2020

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Synthesis of 3-alkyl- or 3-allenyl-2-amidobenzofurans via electrophilic cyclization of o-anisole-substituted ynamides with carbocations

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Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper(II) hydroxide

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Identifiers

DOI

10.1021/JO400960E

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:23718841%20AND%20SRC:MED&resulttype=core&format=json

2 March 2020

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2 March 2020

PubMed publication ID

23718841

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