Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones (Q35015437)

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English	Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones	scientific article

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27 January 2020

Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones (English)

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27 January 2020

Alison J. Frontier

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27 January 2020

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Jie Huang

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27 January 2020

David Lebœuf

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5 April 2011

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27 January 2020

Journal of the American Chemical Society

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27 January 2020

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27 January 2020

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27 January 2020

6307-6317

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27 January 2020

An organocatalytic asymmetric Nazarov cyclization.

1 reference

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8 July 2018

A highly reactive dicationic iridium(III) catalyst for the polarized Nazarov cyclization reaction

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Enamine-iminium ion Nazarov cyclization of alpha-ketoenones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Nazarov cyclization initiated by peracid oxidation: the total synthesis of (+/-)-rocaglamide

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Cyclization of cross-conjugated trienes: the vinylogous Nazarov reaction

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Recent applications of oxazoline-containing ligands in asymmetric catalysis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Formal synthesis of (+/-)-roseophilin

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Traceless chiral auxiliaries for the allene ether Nazarov cyclization

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Asymmetric amine-intercepted Nazarov cyclization

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Intramolecular azide trapping of the Nazarov intermediate: formation of peroxy-bridged indolizidinones via a deep-seated rearrangement and aerobic oxidation

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Strategies for the synthesis of fusicoccanes by Nazarov reactions of dolabelladienones: total synthesis of (+)-fusicoauritone

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

C(2)-symmetric chiral bis(oxazoline) ligands in asymmetric catalysis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Recent developments in the application of oxazoline-containing ligands in asymmetric catalysis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

Catalytic asymmetric Nazarov reactions promoted by chiral Lewis acid complexes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

8 July 2018

A Reductive-Coupling plus Nazarov Cyclization Sequence in the Asymmetric Synthesis of Five-Membered Carbocycles

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Synthesis of the tetracyclic core of tetrapetalone A enabled by a pyrrole reductive alkylation

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Asymmetric Nazarov reaction catalyzed by chiral tris(oxazoline)/copper(II).

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Organocatalytic asymmetric aza-Nazarov cyclization of an azirine.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Tandem Nazarov cyclization-halovinylation of divinyl ketones under Vilsmeier conditions: synthesis of highly substituted cyclopentadienes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

A metal-catalyzed intermolecular [5+2] cycloaddition/Nazarov cyclization sequence and cascade

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

A mild, catalytic and efficient Nazarov cyclization mediated by phosphomolybdic acid

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Nazarov cyclizations of an allenyl vinyl ketone with interception of the oxyallyl cation intermediate for the formation of carbon-carbon bonds.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Application of Nazarov cyclization to access [6-5-6] and [6-5-5]tricyclic core embedded new heterocycles: an easy entry to structures related to taiwaniaquinoids.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Pronounced steric effects of substituents in the nazarov cyclization of aryl dienyl ketones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Polarizing the Nazarov cyclization: the impact of dienone substitution pattern on reactivity and selectivity.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Efficient synthesis of cyclopentenones from enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Interrupted Nazarov cyclization on silica gel.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Enantioselective Nazarov reactions through catalytic asymmetric proton transfer

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Efficient catalysis of Nazarov cyclization using a cationic iridium complex possessing adjacent labile coordination sites.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Polarizing the Nazarov cyclization: efficient catalysis under mild conditions.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

Formal intermolecular 4 + 4 approach to cyclooctanoids: 4 + 3 capture of the Nazarov oxyallyl intermediate with simple 1,3-dienes.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3104681

25 October 2018

An expeditious Nazarov cyclization strategy toward the hydroazulene core of guanacastepene A

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Intermolecular [3 + 3]-Cycloadditions of Azides with the Nazarov Intermediate

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Domino electrocyclization/azide-capture/schmidt rearrangement of dienones: one-step synthesis of dihydropyridones from simple building blocks

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Efficient Nazarov cyclizations of 2-alkoxy-1,4-pentadien-3-ones

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Generation and trapping of cyclopentenylidene gold species: four pathways to polycyclic compounds

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Pyridine-2,6-bis(oxazolines), helpful ligands for asymmetric catalysts

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Copper-Catalyzed Diels−Alder Reactions

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Tandem Nazarov cyclization-michael addition sequence catalyzed by an Ir(III) complex

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Highly efficient trapping of the Nazarov intermediate with substituted arenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Ni(II)-catalyzed enantioselective Nazarov cyclizations

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Studies Directed toward the Synthesis of Hamigeran B: A Catalytic Oxidative Cyclization

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

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Silver and Brønsted acid catalyzed nazarov-type cyclizations to generate benzofulvenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

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A novel approach to the synthesis of bicyclic lactones via an interrupted Nazarov reaction of gem-divinyl dihydrofurans

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Chiral Brønsted Acids in the Catalytic Asymmetric Nazarov Cyclization—The First Enantioselective Organocatalytic Electrocyclic Reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Highly Diastereoselective Cycloisomerization of Acyclic Trienones. The Interrupted Nazarov Reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

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Acid-catalyzed cyclization of 21-benzylidene-16-dehydropregneolone acetate

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

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Gold-catalyzed synthesis of polycyclic enones from carbon tethered 1,3-enynyl carbonyls via tandem heteroenyne metathesis and Nazarov reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Total synthesis of (+/-)-merrilactone A

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Synthesis of 5-hydroxycyclopent-2-enones from allenyl vinyl ketones via an interrupted Nazarov cyclization

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

The palladium(II)-catalyzed Nazarov reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

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A general method for the catalytic nazarov cyclization of heteroaromatic compounds

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Intermolecular Trapping of the Nazarov Intermediate: Domino Electrocyclization/

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

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Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles

1 reference

https://pubmed.ncbi.nlm.nih.gov/21466152

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

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10.1021/JA111504W

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27 January 2020

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27 January 2020

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27 January 2020

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