[go: up one dir, main page]
IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v162y2020icp908-925.html
   My bibliography  Save this article

Hydrogen production via steam reforming of glycerol over Rh/γ-Al2O3 catalysts modified with CeO2, MgO or La2O3

Author

Listed:
  • Charisiou, N.D.
  • Italiano, C.
  • Pino, L.
  • Sebastian, V.
  • Vita, A.
  • Goula, M.A.
Abstract
The glycerol steam reforming (GSR) reaction for hydrogen production was investigated over Rh-based catalysts supported on γ-Al2O3 modified with CeO2, MgO or La2O3. High specific surface area mesoporous supports (Al2O3, CeO2–Al2O3, MgO–Al2O3 and La2O3–Al2O3) were synthesized by the surfactant-assisted co-precipitation method using cetyltrimethylammonium bromide (CTAB) as template. Then, highly dispersed Rh-based catalysts were prepared by the wetness impregnation technique. The physico-chemical properties of the as-prepared supports and catalysts were investigated by N2-physisorption, XRD, ICP-AES, CO-chemisorption, TEM, H2-TPR, CO2-TPD and NH3-TPD measurements. Performance test experiments were carried out in a continuous flow fixed-bed reactor at water-to-glycerol feed ratio (WGFR) of 20:1 (molar), temperatures from 400 °C to 750 °C, weight hourly space velocity of 50,000 ml g−1 h−1 and atmospheric pressure. The stability of all catalysts was also investigated through 12 h time-on-stream (TOS) experiments at 600 °C using a WGFR of 9:1. All catalysts were remarkably stable during TOS with total glycerol conversion of ≈90%, glycerol conversion into gaseous products of ≈45% and H2 selectivity of ≈78%. The final H2 yield for all catalysts was 2.4–2.9 mol H2/mol glycerol. TEM experiments showed that the carbon formed onto the spent catalysts was amorphous and that sintering was mostly avoided during TOS, helping explain the excellent catalytic stability observed. The unpromoted catalyst seems to be following a different reaction pathway than and the promoted ones that depends strongly on the population and kind of acid and basic sites over its surface.

Suggested Citation

  • Charisiou, N.D. & Italiano, C. & Pino, L. & Sebastian, V. & Vita, A. & Goula, M.A., 2020. "Hydrogen production via steam reforming of glycerol over Rh/γ-Al2O3 catalysts modified with CeO2, MgO or La2O3," Renewable Energy, Elsevier, vol. 162(C), pages 908-925.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:908-925
    DOI: 10.1016/j.renene.2020.08.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014812031274X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.08.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    2. Naylor, Rosamond L. & Higgins, Matthew M., 2017. "The political economy of biodiesel in an era of low oil prices," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 695-705.
    3. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    4. Sharma, Yogesh Chandra & Kumar, Ashutosh & Prasad, Ram & Upadhyay, Siddh Nath, 2017. "Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 89-103.
    5. Doumax-Tagliavini, Virginie & Sarasa, Cristina, 2018. "Looking towards policies supporting biofuels and technological change: Evidence from France," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 430-439.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Khademi, Mohammad Hasan & Alipour-Dehkordi, Afshar & Nalchifard, Fereshteh, 2023. "Sustainable hydrogen and syngas production from waste valorization of biodiesel synthesis by-product: Green chemistry approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    2. Wang, Chunsheng & Wang, Yishuang & Chen, Mingqiang & Liang, Defang & Cheng, Wen & Li, Chang & Yang, Zhonglian & Wang, Jun, 2022. "Understanding relationship of sepiolite structure tailoring and the catalytic behaviors in glycerol steam reforming over Co/sepiolite derived Co-phyllosilicate catalyst," Renewable Energy, Elsevier, vol. 183(C), pages 304-320.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Guanyi & Tao, Junyu & Liu, Caixia & Yan, Beibei & Li, Wanqing & Li, Xiangping, 2017. "Hydrogen production via acetic acid steam reforming: A critical review on catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1091-1098.
    2. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    3. Satinover, Scott J. & Schell, Dan & Borole, Abhijeet P., 2020. "Achieving high hydrogen productivities of 20 L/L-day via microbial electrolysis of corn stover fermentation products," Applied Energy, Elsevier, vol. 259(C).
    4. Łukajtis, Rafał & Hołowacz, Iwona & Kucharska, Karolina & Glinka, Marta & Rybarczyk, Piotr & Przyjazny, Andrzej & Kamiński, Marian, 2018. "Hydrogen production from biomass using dark fermentation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 665-694.
    5. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    6. Rochelle, David & Najafi, Hamidreza, 2019. "A review of the effect of biodiesel on gas turbine emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 129-137.
    7. Purnomo, Herry & Kusumadewi, Sonya D. & Ilham, Qori P. & Puspitaloka, Dyah & Hayati, Durrah & Sanjaya, Made & Okarda, Beni & Dewi, Sonya & Dermawan, Ahmad & Brady, Michael A., 2021. "A political-economy model to reduce fire and improve livelihoods in Indonesia's lowlands," Forest Policy and Economics, Elsevier, vol. 130(C).
    8. Severo, Ihana Aguiar & Siqueira, Stefania Fortes & Deprá, Mariany Costa & Maroneze, Mariana Manzoni & Zepka, Leila Queiroz & Jacob-Lopes, Eduardo, 2019. "Biodiesel facilities: What can we address to make biorefineries commercially competitive?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 686-705.
    9. Bilgili, Faik & Kocak, Emrah & Kuskaya, Sevda & Bulut, Umit, 2022. "Co-movements and causalities between ethanol production and corn prices in the USA: New evidence from wavelet transform analysis," Energy, Elsevier, vol. 259(C).
    10. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    11. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    12. Kugelmeier, Cristie Luis & Monteiro, Marcos Roberto & da Silva, Rodrigo & Kuri, Sebastião Elias & Sordi, Vitor Luiz & Della Rovere, Carlos Alberto, 2021. "Corrosion behavior of carbon steel, stainless steel, aluminum and copper upon exposure to biodiesel blended with petrodiesel," Energy, Elsevier, vol. 226(C).
    13. Andrew William Ruttinger & Miyuru Kannangara & Jalil Shadbahr & Phil De Luna & Farid Bensebaa, 2021. "How CO 2 -to-Diesel Technology Could Help Reach Net-Zero Emissions Targets: A Canadian Case Study," Energies, MDPI, vol. 14(21), pages 1-21, October.
    14. Bagheri, Samira & Julkapli, Nurhidayatullaili Muhd & Yehye, Wageeh A., 2015. "Catalytic conversion of biodiesel derived raw glycerol to value added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 113-127.
    15. Abel Rodrigues & João Carlos Bordado & Rui Galhano dos Santos, 2017. "Upgrading the Glycerol from Biodiesel Production as a Source of Energy Carriers and Chemicals—A Technological Review for Three Chemical Pathways," Energies, MDPI, vol. 10(11), pages 1-36, November.
    16. Eugenio Meloni & Marco Martino & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Vincenzo Palma, 2022. "The Route from Green H 2 Production through Bioethanol Reforming to CO 2 Catalytic Conversion: A Review," Energies, MDPI, vol. 15(7), pages 1-36, March.
    17. Robles-Iglesias, Raúl & Naveira-Pazos, Cecilia & Fernández-Blanco, Carla & Veiga, María C. & Kennes, Christian, 2023. "Factors affecting the optimisation and scale-up of lipid accumulation in oleaginous yeasts for sustainable biofuels production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    18. Patrice Bougette & Christophe Charlier, 2019. "Subsidies and Countervailing Measures in the EU Biofuel Industry: A Welfare Analysis," Post-Print halshs-02306022, HAL.
    19. Deng, Yimin & Li, Shuo & Appels, Lise & Zhang, Huili & Sweygers, Nick & Baeyens, Jan & Dewil, Raf, 2023. "Steam reforming of ethanol by non-noble metal catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    20. Liu, Shen & Colson, Gregory & Wetzstein, Michael, 2018. "Biodiesel investment in a disruptive tax-credit policy environment," Energy Policy, Elsevier, vol. 123(C), pages 19-30.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:162:y:2020:i:c:p:908-925. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.