[go: up one dir, main page]
IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v56y2013icp193-206.html
   My bibliography  Save this article

Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst

Author

Listed:
  • Gutiérrez Ortiz, F.J.
  • Serrera, A.
  • Galera, S.
  • Ollero, P.
Abstract
Hydrogen production from the supercritical water reforming of glycerol was studied in a tubular reactor without adding a catalyst. Experiments were carried out at a pressure of 240bar, temperatures of 750–850°C, and glycerol feed concentrations of 5–30wt.%. Likewise, the residence time was changed from 12 to 160s, by handling the feed flow-rate. The dry gas is mainly consisted of H2, CO2, CO, CH4. In addition, small concentrations of glycerol were measured in the liquid phase analysis, but barely traces of others like glycolaldehyde, glyceraldehyde, dihydroxyacetone and lactic acid were detected. Thus, two probable reaction pathways are discussed, which makes it possible to explain the experimental results by using a method applicable to other similar processes. The results showed that the glycerol conversion was almost complete, except at the highest glycerol feed concentration, in which the conversion was of 88%. Hydrogen yields from 2 to 4molH2/molglycerol were obtained at high and low glycerol feed concentrations, respectively, when operating at high temperature and residence time. Besides, it was verified the catalytic effect of the reactor material (Inconel 625) from the trend of the gas product yields with time and the structured carbon nanotubes encountered. The catalytic activity of the reactor material was decreasing to reach a steady state after a few tens of operating hours. This study illustrates that the reforming of glycerol using supercritical water without added catalyst is feasible to achieve a high-yield hydrogen production, and it encourages to continue the research line, to obtain a process economically interesting.

Suggested Citation

  • Gutiérrez Ortiz, F.J. & Serrera, A. & Galera, S. & Ollero, P., 2013. "Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst," Energy, Elsevier, vol. 56(C), pages 193-206.
    • Handle: RePEc:eee:energy:v:56:y:2013:i:c:p:193-206
    DOI: 10.1016/j.energy.2013.04.046
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544213003575
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2013.04.046?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. R. D. Cortright & R. R. Davda & J. A. Dumesic, 2002. "Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water," Nature, Nature, vol. 418(6901), pages 964-967, August.
    2. Unknown, 2005. "Forward," 2005 Conference: Slovenia in the EU - Challenges for Agriculture, Food Science and Rural Affairs, November 10-11, 2005, Moravske Toplice, Slovenia 183804, Slovenian Association of Agricultural Economists (DAES).
    3. Guo, Y. & Wang, S.Z. & Xu, D.H. & Gong, Y.M. & Ma, H.H. & Tang, X.Y., 2010. "Review of catalytic supercritical water gasification for hydrogen production from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 334-343, January.
    4. Guo, L.J. & Zhao, L. & Jing, D.W. & Lu, Y.J. & Yang, H.H. & Bai, B.F. & Zhang, X.M. & Ma, L.J. & Wu, X.M., 2010. "Reprint of: Solar hydrogen production and its development in China," Energy, Elsevier, vol. 35(11), pages 4421-4438.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Jialing & Rong, Siqi & Sun, Jingli & Peng, Zhiyong & Jin, Hui & Guo, Liejin & Zhang, Xiang & Zhou, Teng, 2022. "Optimal design of non-isothermal supercritical water gasification reactor: From biomass to hydrogen," Energy, Elsevier, vol. 244(PB).
    2. Lin, Junhao & Sun, Shichang & Cui, Chongwei & Ma, Rui & Fang, Lin & Zhang, Peixin & Quan, Zonggang & Song, Xin & Yan, Jianglong & Luo, Juan, 2019. "Hydrogen-rich bio-gas generation and optimization in relation to heavy metals immobilization during Pd-catalyzed supercritical water gasification of sludge," Energy, Elsevier, vol. 189(C).
    3. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    4. Setyawan, Hendrix Y. & Zhu, Mingming & Zhang, Zhezi & Zhang, Dongke, 2016. "Ignition and combustion characteristics of single droplets of a crude glycerol in comparison with pure glycerol, petroleum diesel, biodiesel and ethanol," Energy, Elsevier, vol. 113(C), pages 153-159.
    5. Serrera, A. & Gutiérrez Ortiz, F.J. & Ollero, P., 2014. "Syngas methanation from the supercritical water reforming of glycerol," Energy, Elsevier, vol. 76(C), pages 584-592.
    6. Zhang, Fengming & Xu, Chunyan & Zhang, Yong & Chen, Shouyan & Chen, Guifang & Ma, Chunyuan, 2014. "Experimental study on the operating characteristics of an inner preheating transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties," Energy, Elsevier, vol. 66(C), pages 577-587.
    7. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    8. Knez, Ž. & Markočič, E. & Leitgeb, M. & Primožič, M. & Knez Hrnčič, M. & Škerget, M., 2014. "Industrial applications of supercritical fluids: A review," Energy, Elsevier, vol. 77(C), pages 235-243.
    9. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2016. "Supercritical water reforming of glycerol: Performance of Ru and Ni catalysts on Al2O3 support," Energy, Elsevier, vol. 96(C), pages 561-568.
    10. Ojani, Reza & Hasheminejad, Ehteram & Raoof, Jahan Bakhsh, 2015. "Direct growth of 3D flower-like Pt nanostructures by a template-free electrochemical route as an efficient electrocatalyst for methanol oxidation reaction," Energy, Elsevier, vol. 90(P1), pages 1122-1131.
    11. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    12. Florentina Maxim & Iuliana Poenaru & Elena Ecaterina Toma & Giuseppe Stefan Stoian & Florina Teodorescu & Cristian Hornoiu & Speranta Tanasescu, 2021. "Functional Materials for Waste-to-Energy Processes in Supercritical Water," Energies, MDPI, vol. 14(21), pages 1-23, November.
    13. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2015. "Hydrogen production from supercritical water reforming of glycerol over Ni/Al2O3–SiO2 catalyst," Energy, Elsevier, vol. 84(C), pages 634-642.
    14. Ju, Jianfeng & Chen, Xi & Shi, Yujun & Wu, Donghui & Hua, Ping, 2013. "A novel TiO2 nanofiber supported PdAg catalyst for methanol electro-oxidation," Energy, Elsevier, vol. 59(C), pages 478-483.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ane Caroline Pereira Borges & Jude Azubuike Onwudili & Heloysa Andrade & Carine Alves & Andrew Ingram & Silvio Vieira de Melo & Ednildo Torres, 2020. "Catalytic Properties and Recycling of NiFe 2 O 4 Catalyst for Hydrogen Production by Supercritical Water Gasification of Eucalyptus Wood Chips," Energies, MDPI, vol. 13(17), pages 1-17, September.
    2. He, Chao & Chen, Chia-Lung & Giannis, Apostolos & Yang, Yanhui & Wang, Jing-Yuan, 2014. "Hydrothermal gasification of sewage sludge and model compounds for renewable hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 1127-1142.
    3. Su, Hongcai & Yan, Mi & Wang, Shurong, 2022. "Recent advances in supercritical water gasification of biowaste catalyzed by transition metal-based catalysts for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    4. Tekin, Kubilay & Karagöz, Selhan & Bektaş, Sema, 2014. "A review of hydrothermal biomass processing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 673-687.
    5. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.
    6. Hrnčič, Maša Knez & Kravanja, Gregor & Knez, Željko, 2016. "Hydrothermal treatment of biomass for energy and chemicals," Energy, Elsevier, vol. 116(P2), pages 1312-1322.
    7. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    8. Onursal Yakaboylu & John Harinck & K. G. Smit & Wiebren De Jong, 2015. "Supercritical Water Gasification of Biomass: A Literature and Technology Overview," Energies, MDPI, vol. 8(2), pages 1-36, January.
    9. Pilar Lopez-Llompart & G. Mathias Kondolf, 2016. "Encroachments in floodways of the Mississippi River and Tributaries Project," Natural Hazards: Journal of the International Society for the Prevention and Mitigation of Natural Hazards, Springer;International Society for the Prevention and Mitigation of Natural Hazards, vol. 81(1), pages 513-542, March.
    10. Cheng, Jianquan & Bertolini, Luca, 2013. "Measuring urban job accessibility with distance decay, competition and diversity," Journal of Transport Geography, Elsevier, vol. 30(C), pages 100-109.
    11. M. De Donno & M. Pratelli, 2006. "A theory of stochastic integration for bond markets," Papers math/0602532, arXiv.org.
    12. Prilly Oktoviany & Robert Knobloch & Ralf Korn, 2021. "A machine learning-based price state prediction model for agricultural commodities using external factors," Decisions in Economics and Finance, Springer;Associazione per la Matematica, vol. 44(2), pages 1063-1085, December.
    13. Michelle Sheran Sylvester, 2007. "The Career and Family Choices of Women: A Dynamic Analysis of Labor Force Participation, Schooling, Marriage and Fertility Decisions," Review of Economic Dynamics, Elsevier for the Society for Economic Dynamics, vol. 10(3), pages 367-399, July.
    14. Henrekson, Magnus & Johansson, Dan, 2010. "Firm Growth, Institutions and Structural Transformation," Ratio Working Papers 150, The Ratio Institute.
    15. Karen K. Lewis, 2011. "Global Asset Pricing," Annual Review of Financial Economics, Annual Reviews, vol. 3(1), pages 435-466, December.
    16. DAVID M. BLAU & WILBERT van der KLAAUW, 2013. "What Determines Family Structure?," Economic Inquiry, Western Economic Association International, vol. 51(1), pages 579-604, January.
    17. Panagiota DIONYSOPOULOU & Georgios SVARNIAS & Theodore PAPAILIAS, 2021. "Total Quality Management In Public Sector, Case Study: Customs Service," Regional Science Inquiry, Hellenic Association of Regional Scientists, vol. 0(1), pages 153-168, June.
    18. Afanasyev, Dmitriy O. & Fedorova, Elena A. & Popov, Viktor U., 2015. "Fine structure of the price–demand relationship in the electricity market: Multi-scale correlation analysis," Energy Economics, Elsevier, vol. 51(C), pages 215-226.
    19. Peter Viggo Jakobsen, 2009. "Small States, Big Influence: The Overlooked Nordic Influence on the Civilian ESDP," Journal of Common Market Studies, Wiley Blackwell, vol. 47(1), pages 81-102, January.
    20. Julie Holland Mortimer, 2007. "Price Discrimination, Copyright Law, and Technological Innovation: Evidence from the Introduction of DVDs," The Quarterly Journal of Economics, President and Fellows of Harvard College, vol. 122(3), pages 1307-1350.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:56:y:2013:i:c:p:193-206. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.