[go: up one dir, main page]
Wikipedia

Unbihexium

"Ubh" redirects here. For other uses, see UBH (disambiguation).

Unbihexium, also known as element 126 or eka-plutonium, is a hypothetical chemical element; it has atomic number 126 and placeholder symbol Ubh. Unbihexium and Ubh are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbihexium is expected to be a g-block superactinide and the eighth element in the 8th period. Unbihexium has attracted attention among nuclear physicists, especially in early predictions targeting properties of superheavy elements, for 126 may be a magic number of protons near the center of an island of stability, leading to longer half-lives, especially for 310Ubh or 354Ubh which may also have magic numbers of neutrons.[2]

Unbihexium, 126Ubh
Theoretical element
Unbihexium
Pronunciation/ˌuːnbaɪˈhɛksiəm/ ​(OON-by-HEK-see-əm)
Alternative nameselement 126, eka-plutonium
Unbihexium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Ununennium Unbinilium
Unquadtrium Unquadquadium Unquadpentium Unquadhexium Unquadseptium Unquadoctium Unquadennium Unpentnilium Unpentunium Unpentbium Unpenttrium Unpentquadium Unpentpentium Unpenthexium Unpentseptium Unpentoctium Unpentennium Unhexnilium Unhexunium Unhexbium Unhextrium Unhexquadium Unhexpentium Unhexhexium Unhexseptium Unhexoctium Unhexennium Unseptnilium Unseptunium Unseptbium
Unbiunium Unbibium Unbitrium Unbiquadium Unbipentium Unbihexium Unbiseptium Unbioctium Unbiennium Untrinilium Untriunium Untribium Untritrium Untriquadium Untripentium Untrihexium Untriseptium Untrioctium Untriennium Unquadnilium Unquadunium Unquadbium
—
↑
Ubh
↓
—
unbipentium ← unbihexium → unbiseptium
Atomic number (Z)126
Groupg-block groups (no number)
Periodperiod 8 (theoretical, extended table)
Block  g-block
Electron configurationpredictions vary, see text
Physical properties
Phase at STPunknown
Atomic properties
Oxidation statescommon: (none)
(+4), (+6), (+8)[1]
Other properties
CAS Number54500-77-5
History
NamingIUPAC systematic element name
| references

Early interest in possible increased stability led to the first attempted synthesis of unbihexium in 1971 and searches for it in nature in subsequent years. Despite several reported observations, more recent studies suggest that these experiments were insufficiently sensitive; hence, no unbihexium has been found naturally or artificially. Predictions of the stability of unbihexium vary greatly among different models; some suggest the island of stability may instead lie at a lower atomic number, closer to copernicium and flerovium.

Unbihexium is predicted to be a chemically active superactinide, exhibiting a variety of oxidation states from +1 to +8, and possibly being a heavier congener of plutonium. An overlap in energy levels of the 5g, 6f, 7d, and 8p orbitals is also expected, which complicates predictions of chemical properties for this element.

Introduction

edit
This section is an excerpt from Superheavy element § Introduction.[edit]

Synthesis of superheavy nuclei

edit
A graphic depiction of a nuclear fusion reaction 
A graphic depiction of a nuclear fusion reaction. Two nuclei fuse into one, emitting a neutron. Reactions that created new elements to this moment were similar, with the only possible difference that several singular neutrons sometimes were released, or none at all.

A superheavy[a] atomic nucleus is created in a nuclear reaction that combines two other nuclei of unequal size[b] into one; roughly, the more unequal the two nuclei in terms of mass, the greater the possibility that the two react.[8] The material made of the heavier nuclei is made into a target, which is then bombarded by the beam of lighter nuclei. Two nuclei can only fuse into one if they approach each other closely enough; normally, nuclei (all positively charged) repel each other due to electrostatic repulsion. The strong interaction can overcome this repulsion but only within a very short distance from a nucleus; beam nuclei are thus greatly accelerated in order to make such repulsion insignificant compared to the velocity of the beam nucleus.[9] The energy applied to the beam nuclei to accelerate them can cause them to reach speeds as high as one-tenth of the speed of light. However, if too much energy is applied, the beam nucleus can fall apart.[9]

Coming close enough alone is not enough for two nuclei to fuse: when two nuclei approach each other, they usually remain together for about 10−20 seconds and then part ways (not necessarily in the same composition as before the reaction) rather than form a single nucleus.[9][10] This happens because during the attempted formation of a single nucleus, electrostatic repulsion tears apart the nucleus that is being formed.[9] Each pair of a target and a beam is characterized by its cross section—the probability that fusion will occur if two nuclei approach one another expressed in terms of the transverse area that the incident particle must hit in order for the fusion to occur.[c] This fusion may occur as a result of the quantum effect in which nuclei can tunnel through electrostatic repulsion. If the two nuclei can stay close past that phase, multiple nuclear interactions result in redistribution of energy and an energy equilibrium.[9]

External videos
video icon  Visualization of unsuccessful nuclear fusion, based on calculations from the Australian National University[12]

The resulting merger is an excited state[13]—termed a compound nucleus—and thus it is very unstable.[9] To reach a more stable state, the temporary merger may fission without formation of a more stable nucleus.[14] Alternatively, the compound nucleus may eject a few neutrons, which would carry away the excitation energy; if the latter is not sufficient for a neutron expulsion, the merger would produce a gamma ray. This happens in about 10−16 seconds after the initial nuclear collision and results in creation of a more stable nucleus.[14] The definition by the IUPAC/IUPAP Joint Working Party (JWP) states that a chemical element can only be recognized as discovered if a nucleus of it has not decayed within 10−14 seconds. This value was chosen as an estimate of how long it takes a nucleus to acquire electrons and thus display its chemical properties.[15][d]

Decay and detection

edit

The beam passes through the target and reaches the next chamber, the separator; if a new nucleus is produced, it is carried with this beam.[17] In the separator, the newly produced nucleus is separated from other nuclides (that of the original beam and any other reaction products)[e] and transferred to a surface-barrier detector, which stops the nucleus. The exact location of the upcoming impact on the detector is marked; also marked are its energy and the time of the arrival.[17] The transfer takes about 10−6 seconds; in order to be detected, the nucleus must survive this long.[20] The nucleus is recorded again once its decay is registered, and the location, the energy, and the time of the decay are measured.[17]

Stability of a nucleus is provided by the strong interaction. However, its range is very short; as nuclei become larger, its influence on the outermost nucleons (protons and neutrons) weakens. At the same time, the nucleus is torn apart by electrostatic repulsion between protons, and its range is not limited.[21] Total binding energy provided by the strong interaction increases linearly with the number of nucleons, whereas electrostatic repulsion increases with the square of the atomic number, i.e. the latter grows faster and becomes increasingly important for heavy and superheavy nuclei.[22][23] Superheavy nuclei are thus theoretically predicted[24] and have so far been observed[25] to predominantly decay via decay modes that are caused by such repulsion: alpha decay and spontaneous fission.[f] Almost all alpha emitters have over 210 nucleons,[27] and the lightest nuclide primarily undergoing spontaneous fission has 238.[28] In both decay modes, nuclei are inhibited from decaying by corresponding energy barriers for each mode, but they can be tunneled through.[22][23]

Apparatus for creation of superheavy elements 
Scheme of an apparatus for creation of superheavy elements, based on the Dubna Gas-Filled Recoil Separator set up in the Flerov Laboratory of Nuclear Reactions in JINR. The trajectory within the detector and the beam focusing apparatus changes because of a dipole magnet in the former and quadrupole magnets in the latter.[29]

Alpha particles are commonly produced in radioactive decays because the mass of an alpha particle per nucleon is small enough to leave some energy for the alpha particle to be used as kinetic energy to leave the nucleus.[30] Spontaneous fission is caused by electrostatic repulsion tearing the nucleus apart and produces various nuclei in different instances of identical nuclei fissioning.[23] As the atomic number increases, spontaneous fission rapidly becomes more important: spontaneous fission partial half-lives decrease by 23 orders of magnitude from uranium (element 92) to nobelium (element 102),[31] and by 30 orders of magnitude from thorium (element 90) to fermium (element 100).[32] The earlier liquid drop model thus suggested that spontaneous fission would occur nearly instantly due to disappearance of the fission barrier for nuclei with about 280 nucleons.[23][33] The later nuclear shell model suggested that nuclei with about 300 nucleons would form an island of stability in which nuclei will be more resistant to spontaneous fission and will primarily undergo alpha decay with longer half-lives.[23][33] Subsequent discoveries suggested that the predicted island might be further than originally anticipated; they also showed that nuclei intermediate between the long-lived actinides and the predicted island are deformed, and gain additional stability from shell effects.[34] Experiments on lighter superheavy nuclei,[35] as well as those closer to the expected island,[31] have shown greater than previously anticipated stability against spontaneous fission, showing the importance of shell effects on nuclei.[g]

Alpha decays are registered by the emitted alpha particles, and the decay products are easy to determine before the actual decay; if such a decay or a series of consecutive decays produces a known nucleus, the original product of a reaction can be easily determined.[h] (That all decays within a decay chain were indeed related to each other is established by the location of these decays, which must be in the same place.)[17] The known nucleus can be recognized by the specific characteristics of decay it undergoes such as decay energy (or more specifically, the kinetic energy of the emitted particle).[i] Spontaneous fission, however, produces various nuclei as products, so the original nuclide cannot be determined from its daughters.[j]

The information available to physicists aiming to synthesize a superheavy element is thus the information collected at the detectors: location, energy, and time of arrival of a particle to the detector, and those of its decay. The physicists analyze this data and seek to conclude that it was indeed caused by a new element and could not have been caused by a different nuclide than the one claimed. Often, provided data is insufficient for a conclusion that a new element was definitely created and there is no other explanation for the observed effects; errors in interpreting data have been made.[k]

History

edit

Synthesis attempts

edit

The first and only attempt to synthesize unbihexium, which was unsuccessful, was performed in 1971 at CERN (European Organization for Nuclear Research) by René Bimbot and John M. Alexander using the hot fusion reaction:[2][46]

232
90Th
 + 84
36Kr
 → 316
126Ubh
* → no atoms

High-energy (13-15 MeV) alpha particles were observed and taken as possible evidence for the synthesis of unbihexium. Subsequent unsuccessful experiments with higher sensitivity suggest that the 10 mb sensitivity of this experiment was too low; hence, the formation of unbihexium nuclei in this reaction was deemed highly unlikely.[47]

Possible natural occurrence

edit

A study in 1976 by a group of American researchers from several universities proposed that primordial superheavy elements, mainly livermorium, unbiquadium, unbihexium, and unbiseptium, with half-lives exceeding 500 million years[48] could be a cause of unexplained radiation damage (particularly radiohalos) in minerals.[49] This prompted many researchers to search for them in nature from 1976 to 1983. A group led by Tom Cahill, a professor at the University of California at Davis, claimed in 1976 that they had detected alpha particles and X-rays with the right energies to cause the damage observed, supporting the presence of these elements, especially unbihexium. Others claimed that none had been detected, and questioned the proposed characteristics of primordial superheavy nuclei.[50] In particular, they cited that the magic number N = 228 necessary for enhanced stability would create a neutron-excessive nucleus in unbihexium that might not be beta-stable, although several calculations suggest that 354Ubh may indeed be stable against beta decay.[51] This activity was also proposed to be caused by nuclear transmutations in natural cerium, raising further ambiguity upon this claimed observation of superheavy elements.[52]

Unbihexium has received particular attention in these investigations, for its speculated location in the island of stability may increase its abundance relative to other superheavy elements.[48] Any naturally occurring unbihexium is predicted to be chemically similar to plutonium and may exist with primordial 244Pu in the rare earth mineral bastnäsite.[48] In particular, plutonium and unbihexium are predicted to have similar valence configurations, leading to the existence of unbihexium in the +4 oxidation state. Therefore, should unbihexium occur naturally, it may be possible to extract it using similar techniques for the accumulation of cerium and plutonium.[48] Likewise, unbihexium could also exist in monazite with other lanthanides and actinides that would be chemically similar.[52] Recent doubt on the existence of primordial 244Pu casts uncertainty on these predictions, however,[53] as the nonexistence (or minimal existence) of plutonium in bastnäsite will inhibit possible identification of unbihexium as its heavier congener.

The possible extent of primordial superheavy elements on Earth today is uncertain. Even if they are confirmed to have caused the radiation damage long ago, they might now have decayed to mere traces, or even be completely gone.[54] It is also uncertain if such superheavy nuclei may be produced naturally at all, as spontaneous fission is expected to terminate the r-process responsible for heavy element formation between mass number 270 and 290, well before elements such as unbihexium may be formed.[55]

A recent hypothesis tries to explain the spectrum of Przybylski's Star by naturally occurring flerovium, unbinilium, and unbihexium.[56][57]

Naming

edit

Using the 1979 IUPAC recommendations, the element should be temporarily called unbihexium (symbol Ubh) until it is discovered, the discovery is confirmed, and a permanent name chosen.[58] Although widely used in the chemical community on all levels, from chemistry classrooms to advanced textbooks, the recommendations are mostly ignored among scientists who work theoretically or experimentally on superheavy elements, who call it "element 126", with the symbol E126, (126), or 126.[59] Some researchers have also referred to unbihexium as eka-plutonium,[60][61] a name derived from the system Dmitri Mendeleev used to predict unknown elements, though such an extrapolation might not work for g-block elements with no known congeners, and eka-plutonium would instead refer to element 146[62] or 148[63] when the term is meant to denote the element directly below plutonium.

Prospects for future synthesis

edit

Every element from mendelevium onward was produced in fusion-evaporation reactions, culminating in the discovery of the heaviest known element, oganesson, in 2002[64][65] and most recently tennessine in 2010.[66] These reactions approached the limit of current technology; for example, the synthesis of tennessine required 22 milligrams of 249Bk and an intense 48Ca beam for six months. The intensity of beams in superheavy element research cannot exceed 1012 projectiles per second without damaging the target and detector, and producing larger quantities of increasingly rare and unstable actinide targets is impractical.[67] Consequently, future experiments must be done at facilities such as the superheavy element factory (SHE-factory) at the Joint Institute for Nuclear Research (JINR) or RIKEN, which will allow experiments to run for longer time periods with increased detection capabilities and enable otherwise inaccessible reactions.[68] Even so, it will likely be a great challenge to synthesize elements beyond unbinilium (120) or unbiunium (121), given their short predicted half-lives and low predicted cross sections.[69]

It has been suggested that fusion-evaporation will not be feasible to reach unbihexium. As 48Ca cannot be used for synthesis of elements beyond atomic number 118 or possibly 119, the only alternatives are increasing the atomic number of the projectile or studying symmetric or near-symmetric reactions.[70] One calculation suggests that the cross section for producing unbihexium from 249Cf and 64Ni may be as low as nine orders of magnitude lower than the detection limit; such results are also suggested by the non-observation of unbinilium and unbibium in reactions with heavier projectiles and experimental cross section limits.[71] If Z = 126 represents a closed proton shell, compound nuclei may have greater survival probability and the use of 64Ni may be more feasible for producing nuclei with 122 < Z < 126, especially for compound nuclei near the closed shell at N = 184.[72] However, the cross section still might not exceed 1 fb, posing an obstacle that may only be overcome with more sensitive equipment.[73]

Predicted properties

edit

Nuclear stability and isotopes

edit
 
This nuclear chart used by the Japan Atomic Energy Agency predicts the decay modes of nuclei up to Z = 149 and N = 256. At Z = 126 (top right), the beta-stability line passes through a region of instability towards spontaneous fission (half-lives less than 1 nanosecond) and extends into a "cape" of stability near the N = 228 shell closure, where an island of stability centered at the possibly doubly magic isotope 354Ubh may exist.[74]
 
This diagram depicts shell gaps in the nuclear shell model. Shell gaps are created when more energy is required to reach the shell at the next higher energy level, thus resulting in a particularly stable configuration. For protons, the shell gap at Z = 82 corresponds to the peak of stability at lead, and while there is disagreement of the magicity of Z = 114 and Z = 120, a shell gap appears at Z = 126, thus suggesting that there may be a proton shell closure at unbihexium.[75]

Extensions of the nuclear shell model predicted that the next magic numbers after Z = 82 and N = 126 (corresponding to 208Pb, the heaviest stable nucleus) were Z = 126 and N = 184, making 310Ubh the next candidate for a doubly magic nucleus. These speculations led to interest in the stability of unbihexium as early as 1957; Gertrude Scharff Goldhaber was one of the first physicists to predict a region of increased stability in the vicinity of, and possibly centered at, unbihexium.[2] This notion of an "island of stability" comprising longer-lived superheavy nuclei was popularized by University of California professor Glenn Seaborg in the 1960s.[76]

In this region of the periodic table, N = 184 and N = 228 have been suggested as closed neutron shells,[77] and various atomic numbers, including Z = 126, have been proposed as closed proton shells.[l] The extent of stabilizing effects in the region of unbihexium is uncertain, however, due to predictions of shifting or weakening of the proton shell closure and possible loss of double magicity.[77] More recent research predicts the island of stability to instead be centered at beta-stable isotopes of copernicium (291Cn and 293Cn)[70][78] or flerovium (Z = 114), which would place unbihexium well above the island and result in short half-lives regardless of shell effects.

Earlier models suggested the existence of long-lived nuclear isomers resistant to spontaneous fission in the region near 310Ubh, with half-lives on the order of millions or billions of years.[79] However, more rigorous calculations as early as the 1970s yielded contradictory results; it is now believed that the island of stability is not centered at 310Ubh, and thus will not enhance the stability of this nuclide. Instead, 310Ubh is thought to be very neutron-deficient and susceptible to alpha decay and spontaneous fission in less than a microsecond, and it may even lie at or beyond the proton drip line.[2][69][74] A 2016 calculation on the decay properties of 288–339Ubh upholds these predictions; the isotopes lighter than 313Ubh (including 310Ubh) may indeed lie beyond the drip line and decay by proton emission, 313–327Ubh will alpha decay, possibly reaching flerovium and livermorium isotopes, and heavier isotopes will decay by spontaneous fission.[80] This study and a quantum tunneling model predict alpha-decay half-lives under a microsecond for isotopes lighter than 318Ubh, rendering them impossible to identify experimentally.[80][81][m] Hence, the isotopes 318–327Ubh may be synthesized and detected, and may even constitute a region of increased stability against fission around N ~ 198 with half-lives up to several seconds, though such a region of increased stability is completely absent in other models.[78]

A "sea of instability" defined by very low fission barriers (caused by greatly increasing Coulomb repulsion in superheavy elements) and consequently fission half-lives on the order of 10−18 seconds is predicted across various models. Although the exact limit of stability for half-lives over one microsecond varies, stability against fission is strongly dependent on the N = 184 and N = 228 shell closures and rapidly drops off immediately beyond the influence of the shell closure.[69][74] Such an effect may be reduced, however, if nuclear deformation in intermediate isotopes may lead to a shift in magic numbers;[82] a similar phenomenon was observed in the deformed doubly magic nucleus 270Hs.[83] This shift could then lead to longer half-lives, perhaps on the order of days, for isotopes such as 342Ubh that would also lie on the beta-stability line.[82] A second island of stability for spherical nuclei may exist in unbihexium isotopes with many more neutrons, centered at 354Ubh and conferring additional stability in N = 228 isotones near the beta-stability line.[74] Originally, a short half-life of 39 milliseconds was predicted for 354Ubh toward spontaneous fission, though a partial alpha half-life for this isotope was predicted to be 18 years.[2] More recent analysis suggests that this isotope may have a half-life on the order of 100 years should the closed shells have strong stabilizing effects, placing it at the peak of an island of stability.[74] It may also be possible that 354Ubh is not doubly magic, as the Z = 126 shell is predicted to be relatively weak, or in some calculations, completely nonexistent. This suggests that any relative stability in unbihexium isotopes would be only due to neutron shell closures that may or may not have a stabilizing effect at Z = 126.[51][77]

Chemical

edit

Unbihexium is expected to be the sixth member of a superactinide series. It may have similarities to plutonium, as both elements have eight valence electrons over a noble gas core. In the superactinide series, the Aufbau principle is expected to break down due to relativistic effects, and an overlap of the energy levels of the 7d, 8p, and especially 5g and 6f orbitals is expected, which renders predictions of chemical and atomic properties of these elements very difficult.[84] The ground state electron configuration of unbihexium is thus predicted to be [Og] 5g2 6f2 7d1 8s2 8p1[85] or 5g1 6f4 8s2 8p1,[86] in contrast to [Og] 5g6 8s2 derived from Aufbau.

As with the other early superactinides, it is predicted that unbihexium will be able to lose all eight valence electrons in chemical reactions, rendering a variety of oxidation states up to +8 possible.[1] The +4 oxidation state is predicted to be most common, in addition to +2 and +6.[85][62] Unbihexium should be able to form the tetroxide UbhO4 and hexahalides UbhF6 and UbhCl6, the latter with a fairly strong bond dissociation energy of 2.68 eV.[87] Calculations suggest that a diatomic UbhF molecule will feature a bond between the 5g orbital in unbihexium and the 2p orbital in fluorine, thus characterizing unbihexium as an element whose 5g electrons should actively participate in bonding.[60][61] It is also predicted that the Ubh6+ (in particular, in UbhF6) and Ubh7+ ions will have the electron configurations [Og] 5g2 and [Og] 5g1, respectively, in contrast to the [Og] 6f1 configuration seen in Ubt4+ and Ubq5+ that bears more resemblance to their actinide homologs.[1] The activity of 5g electrons may influence the chemistry of superactinides such as unbihexium in new ways that are difficult to predict, as no known elements have electrons in a g orbital in the ground state.[62]

See also

edit

Notes

edit
  1. ^ In nuclear physics, an element is called heavy if its atomic number is high; lead (element 82) is one example of such a heavy element. The term "superheavy elements" typically refers to elements with atomic number greater than 103 (although there are other definitions, such as atomic number greater than 100[3] or 112;[4] sometimes, the term is presented an equivalent to the term "transactinide", which puts an upper limit before the beginning of the hypothetical superactinide series).[5] Terms "heavy isotopes" (of a given element) and "heavy nuclei" mean what could be understood in the common language—isotopes of high mass (for the given element) and nuclei of high mass, respectively.
  2. ^ In 2009, a team at the JINR led by Oganessian published results of their attempt to create hassium in a symmetric 136Xe + 136Xe reaction. They failed to observe a single atom in such a reaction, putting the upper limit on the cross section, the measure of probability of a nuclear reaction, as 2.5 pb.[6] In comparison, the reaction that resulted in hassium discovery, 208Pb + 58Fe, had a cross section of ~20 pb (more specifically, 19+19
    -11     pb), as estimated by the discoverers.[7]
  3. ^ The amount of energy applied to the beam particle to accelerate it can also influence the value of cross section. For example, in the 28
    14    Si
     + 1
    0    n
     → 28
    13    Al
     + 1
    1    p
     reaction, cross section changes smoothly from 370 mb at 12.3 MeV to 160 mb at 18.3 MeV, with a broad peak at 13.5 MeV with the maximum value of 380 mb.[11]
  4. ^ This figure also marks the generally accepted upper limit for lifetime of a compound nucleus.[16]
  5. ^ This separation is based on that the resulting nuclei move past the target more slowly then the unreacted beam nuclei. The separator contains electric and magnetic fields whose effects on a moving particle cancel out for a specific velocity of a particle.[18] Such separation can also be aided by a time-of-flight measurement and a recoil energy measurement; a combination of the two may allow to estimate the mass of a nucleus.[19]
  6. ^ Not all decay modes are caused by electrostatic repulsion. For example, beta decay is caused by the weak interaction.[26]
  7. ^ It was already known by the 1960s that ground states of nuclei differed in energy and shape as well as that certain magic numbers of nucleons corresponded to greater stability of a nucleus. However, it was assumed that there was no nuclear structure in superheavy nuclei as they were too deformed to form one.[31]
  8. ^ Since mass of a nucleus is not measured directly but is rather calculated from that of another nucleus, such measurement is called indirect. Direct measurements are also possible, but for the most part they have remained unavailable for superheavy nuclei.[36] The first direct measurement of mass of a superheavy nucleus was reported in 2018 at LBNL.[37] Mass was determined from the location of a nucleus after the transfer (the location helps determine its trajectory, which is linked to the mass-to-charge ratio of the nucleus, since the transfer was done in presence of a magnet).[38]
  9. ^ If the decay occurred in a vacuum, then since total momentum of an isolated system before and after the decay must be preserved, the daughter nucleus would also receive a small velocity. The ratio of the two velocities, and accordingly the ratio of the kinetic energies, would thus be inverse to the ratio of the two masses. The decay energy equals the sum of the known kinetic energy of the alpha particle and that of the daughter nucleus (an exact fraction of the former).[27] The calculations hold for an experiment as well, but the difference is that the nucleus does not move after the decay because it is tied to the detector.
  10. ^ Spontaneous fission was discovered by Soviet physicist Georgy Flerov,[39] a leading scientist at JINR, and thus it was a "hobbyhorse" for the facility.[40] In contrast, the LBL scientists believed fission information was not sufficient for a claim of synthesis of an element. They believed spontaneous fission had not been studied enough to use it for identification of a new element, since there was a difficulty of establishing that a compound nucleus had only ejected neutrons and not charged particles like protons or alpha particles.[16] They thus preferred to link new isotopes to the already known ones by successive alpha decays.[39]
  11. ^ For instance, element 102 was mistakenly identified in 1957 at the Nobel Institute of Physics in Stockholm, Stockholm County, Sweden.[41] There were no earlier definitive claims of creation of this element, and the element was assigned a name by its Swedish, American, and British discoverers, nobelium. It was later shown that the identification was incorrect.[42] The following year, RL was unable to reproduce the Swedish results and announced instead their synthesis of the element; that claim was also disproved later.[42] JINR insisted that they were the first to create the element and suggested a name of their own for the new element, joliotium;[43] the Soviet name was also not accepted (JINR later referred to the naming of the element 102 as "hasty").[44] This name was proposed to IUPAC in a written response to their ruling on priority of discovery claims of elements, signed 29 September 1992.[44] The name "nobelium" remained unchanged on account of its widespread usage.[45]
  12. ^ Atomic numbers 114, 120, 122, 124 have also been suggested as closed proton shells in different models.
  13. ^ While such nuclei may be synthesized and a series of decay signals may be registered, decays faster than one microsecond may pile up with subsequent signals and thus be indistinguishable, especially when multiple uncharacterized nuclei may be formed and emit a series of similar alpha particles. The main difficulty is thus attributing the decays to the correct parent nucleus, as a superheavy atom that decays before reaching the detector will not be registered at all.

References

edit
  1. ^ a b c Pyykkö, Pekka (2011). "A suggested periodic table up to Z ≤ 172, based on Dirac–Fock calculations on atoms and ions". Physical Chemistry Chemical Physics. 13 (1): 161–8. Bibcode:2011PCCP...13..161P. doi:10.1039/c0cp01575j. PMID 20967377.
  2. ^ a b c d e Bemis, C.E.; Nix, J.R. (1977). "Superheavy elements - the quest in perspective" (PDF). Comments on Nuclear and Particle Physics. 7 (3): 65–78. ISSN 0010-2709.
  3. ^ Krämer, K. (2016). "Explainer: superheavy elements". Chemistry World. Retrieved 2020-03-15.
  4. ^ "Discovery of Elements 113 and 115". Lawrence Livermore National Laboratory. Archived from the original on 2015-09-11. Retrieved 2020-03-15.
  5. ^ Eliav, E.; Kaldor, U.; Borschevsky, A. (2018). "Electronic Structure of the Transactinide Atoms". In Scott, R. A. (ed.). Encyclopedia of Inorganic and Bioinorganic Chemistry. John Wiley & Sons. pp. 1–16. doi:10.1002/9781119951438.eibc2632. ISBN 978-1-119-95143-8. S2CID 127060181.
  6. ^ Oganessian, Yu. Ts.; Dmitriev, S. N.; Yeremin, A. V.; et al. (2009). "Attempt to produce the isotopes of element 108 in the fusion reaction 136Xe + 136Xe". Physical Review C. 79 (2): 024608. doi:10.1103/PhysRevC.79.024608. ISSN 0556-2813.
  7. ^ Münzenberg, G.; Armbruster, P.; Folger, H.; et al. (1984). "The identification of element 108" (PDF). Zeitschrift für Physik A. 317 (2): 235–236. Bibcode:1984ZPhyA.317..235M. doi:10.1007/BF01421260. S2CID 123288075. Archived from the original (PDF) on 7 June 2015. Retrieved 20 October 2012.
  8. ^ Subramanian, S. (28 August 2019). "Making New Elements Doesn't Pay. Just Ask This Berkeley Scientist". Bloomberg Businessweek. Retrieved 2020-01-18.
  9. ^ a b c d e f Ivanov, D. (2019). "Сверхтяжелые шаги в неизвестное" [Superheavy steps into the unknown]. nplus1.ru (in Russian). Retrieved 2020-02-02.
  10. ^ Hinde, D. (2017). "Something new and superheavy at the periodic table". The Conversation. Retrieved 2020-01-30.
  11. ^ Kern, B. D.; Thompson, W. E.; Ferguson, J. M. (1959). "Cross sections for some (n, p) and (n, α) reactions". Nuclear Physics. 10: 226–234. Bibcode:1959NucPh..10..226K. doi:10.1016/0029-5582(59)90211-1.
  12. ^ Wakhle, A.; Simenel, C.; Hinde, D. J.; et al. (2015). Simenel, C.; Gomes, P. R. S.; Hinde, D. J.; et al. (eds.). "Comparing Experimental and Theoretical Quasifission Mass Angle Distributions". European Physical Journal Web of Conferences. 86: 00061. Bibcode:2015EPJWC..8600061W. doi:10.1051/epjconf/20158600061. hdl:1885/148847. ISSN 2100-014X.
  13. ^ "Nuclear Reactions" (PDF). pp. 7–8. Retrieved 2020-01-27. Published as Loveland, W. D.; Morrissey, D. J.; Seaborg, G. T. (2005). "Nuclear Reactions". Modern Nuclear Chemistry. John Wiley & Sons, Inc. pp. 249–297. doi:10.1002/0471768626.ch10. ISBN 978-0-471-76862-3.
  14. ^ a b Krása, A. (2010). "Neutron Sources for ADS". Faculty of Nuclear Sciences and Physical Engineering. Czech Technical University in Prague: 4–8. S2CID 28796927.
  15. ^ Wapstra, A. H. (1991). "Criteria that must be satisfied for the discovery of a new chemical element to be recognized" (PDF). Pure and Applied Chemistry. 63 (6): 883. doi:10.1351/pac199163060879. ISSN 1365-3075. S2CID 95737691.
  16. ^ a b Hyde, E. K.; Hoffman, D. C.; Keller, O. L. (1987). "A History and Analysis of the Discovery of Elements 104 and 105". Radiochimica Acta. 42 (2): 67–68. doi:10.1524/ract.1987.42.2.57. ISSN 2193-3405. S2CID 99193729.
  17. ^ a b c d Chemistry World (2016). "How to Make Superheavy Elements and Finish the Periodic Table [Video]". Scientific American. Retrieved 2020-01-27.
  18. ^ Hoffman, Ghiorso & Seaborg 2000, p. 334.
  19. ^ Hoffman, Ghiorso & Seaborg 2000, p. 335.
  20. ^ Zagrebaev, Karpov & Greiner 2013, p. 3.
  21. ^ Beiser 2003, p. 432.
  22. ^ a b Pauli, N. (2019). "Alpha decay" (PDF). Introductory Nuclear, Atomic and Molecular Physics (Nuclear Physics Part). Université libre de Bruxelles. Retrieved 2020-02-16.
  23. ^ a b c d e Pauli, N. (2019). "Nuclear fission" (PDF). Introductory Nuclear, Atomic and Molecular Physics (Nuclear Physics Part). Université libre de Bruxelles. Retrieved 2020-02-16.
  24. ^ Staszczak, A.; Baran, A.; Nazarewicz, W. (2013). "Spontaneous fission modes and lifetimes of superheavy elements in the nuclear density functional theory". Physical Review C. 87 (2): 024320–1. arXiv:1208.1215. Bibcode:2013PhRvC..87b4320S. doi:10.1103/physrevc.87.024320. ISSN 0556-2813.
  25. ^ Audi et al. 2017, pp. 030001-129–030001-138.
  26. ^ Beiser 2003, p. 439.
  27. ^ a b Beiser 2003, p. 433.
  28. ^ Audi et al. 2017, p. 030001-125.
  29. ^ Aksenov, N. V.; Steinegger, P.; Abdullin, F. Sh.; et al. (2017). "On the volatility of nihonium (Nh, Z = 113)". The European Physical Journal A. 53 (7): 158. Bibcode:2017EPJA...53..158A. doi:10.1140/epja/i2017-12348-8. ISSN 1434-6001. S2CID 125849923.
  30. ^ Beiser 2003, p. 432–433.
  31. ^ a b c Oganessian, Yu. (2012). "Nuclei in the "Island of Stability" of Superheavy Elements". Journal of Physics: Conference Series. 337 (1): 012005-1–012005-6. Bibcode:2012JPhCS.337a2005O. doi:10.1088/1742-6596/337/1/012005. ISSN 1742-6596.
  32. ^ Moller, P.; Nix, J. R. (1994). Fission properties of the heaviest elements (PDF). Dai 2 Kai Hadoron Tataikei no Simulation Symposium, Tokai-mura, Ibaraki, Japan. University of North Texas. Retrieved 2020-02-16.
  33. ^ a b Oganessian, Yu. Ts. (2004). "Superheavy elements". Physics World. 17 (7): 25–29. doi:10.1088/2058-7058/17/7/31. Retrieved 2020-02-16.
  34. ^ Schädel, M. (2015). "Chemistry of the superheavy elements". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences. 373 (2037): 20140191. Bibcode:2015RSPTA.37340191S. doi:10.1098/rsta.2014.0191. ISSN 1364-503X. PMID 25666065.
  35. ^ Hulet, E. K. (1989). Biomodal spontaneous fission. 50th Anniversary of Nuclear Fission, Leningrad, USSR. Bibcode:1989nufi.rept...16H.
  36. ^ Oganessian, Yu. Ts.; Rykaczewski, K. P. (2015). "A beachhead on the island of stability". Physics Today. 68 (8): 32–38. Bibcode:2015PhT....68h..32O. doi:10.1063/PT.3.2880. ISSN 0031-9228. OSTI 1337838. S2CID 119531411.
  37. ^ Grant, A. (2018). "Weighing the heaviest elements". Physics Today. doi:10.1063/PT.6.1.20181113a. S2CID 239775403.
  38. ^ Howes, L. (2019). "Exploring the superheavy elements at the end of the periodic table". Chemical & Engineering News. Retrieved 2020-01-27.
  39. ^ a b Robinson, A. E. (2019). "The Transfermium Wars: Scientific Brawling and Name-Calling during the Cold War". Distillations. Retrieved 2020-02-22.
  40. ^ "Популярная библиотека химических элементов. Сиборгий (экавольфрам)" [Popular library of chemical elements. Seaborgium (eka-tungsten)]. n-t.ru (in Russian). Retrieved 2020-01-07. Reprinted from "Экавольфрам" [Eka-tungsten]. Популярная библиотека химических элементов. Серебро – Нильсборий и далее [Popular library of chemical elements. Silver through nielsbohrium and beyond] (in Russian). Nauka. 1977.
  41. ^ "Nobelium - Element information, properties and uses | Periodic Table". Royal Society of Chemistry. Retrieved 2020-03-01.
  42. ^ a b Kragh 2018, pp. 38–39.
  43. ^ Kragh 2018, p. 40.
  44. ^ a b Ghiorso, A.; Seaborg, G. T.; Oganessian, Yu. Ts.; et al. (1993). "Responses on the report 'Discovery of the Transfermium elements' followed by reply to the responses by Transfermium Working Group" (PDF). Pure and Applied Chemistry. 65 (8): 1815–1824. doi:10.1351/pac199365081815. S2CID 95069384. Archived (PDF) from the original on 25 November 2013. Retrieved 7 September 2016.
  45. ^ Commission on Nomenclature of Inorganic Chemistry (1997). "Names and symbols of transfermium elements (IUPAC Recommendations 1997)" (PDF). Pure and Applied Chemistry. 69 (12): 2471–2474. doi:10.1351/pac199769122471.
  46. ^ Emsley, John (2011). Nature's Building Blocks: An A-Z Guide to the Elements (New ed.). New York, NY: Oxford University Press. p. 588. ISBN 978-0-19-960563-7.
  47. ^ Hoffman, Ghiorso & Seaborg 2000, pp. 404–405.
  48. ^ a b c d Sheline, R.K. (1976). "A Suggested Source of Element 126". Zeitschrift für Physik A. 279 (3): 255–257. Bibcode:1976ZPhyA.279..255S. doi:10.1007/BF01408296. S2CID 121290613.
  49. ^ Hoffman, Ghiorso & Seaborg 2000, p. 413.
  50. ^ Hoffman, Ghiorso & Seaborg 2000, p. 416–417.
  51. ^ a b Lodhi, M.A.K., ed. (March 1978). Superheavy Elements: Proceedings of the International Symposium on Superheavy Elements. Lubbock, Texas: Pergamon Press. ISBN 0-08-022946-8.
  52. ^ a b Hoffman, Ghiorso & Seaborg 2000, p. 417.
  53. ^ Lachner, J.; et al. (2012). "Attempt to detect primordial 244Pu on Earth". Physical Review C. 85 (1). 015801. Bibcode:2012PhRvC..85a5801L. doi:10.1103/PhysRevC.85.015801.
  54. ^ Emsley, John (2011). Nature's Building Blocks: An A–Z Guide to the Elements (New ed.). New York: Oxford University Press. p. 592. ISBN 978-0-19-960563-7.
  55. ^ Petermann, I; Langanke, K.; Martínez-Pinedo, G.; Panov, I.V.; Reinhard, P.G.; Thielemann, F.K. (2012). "Have superheavy elements been produced in nature?". European Physical Journal A. 48 (122): 122. arXiv:1207.3432. Bibcode:2012EPJA...48..122P. doi:10.1140/epja/i2012-12122-6. S2CID 254119199.
  56. ^ Jason Wright (16 March 2017). "Przybylski's Star III: Neutron Stars, Unbinilium, and aliens". Retrieved 31 July 2018.
  57. ^ V. A. Dzuba; V. V. Flambaum; J. K. Webb (2017). "Isotope shift and search for metastable superheavy elements in astrophysical data". Physical Review A. 95 (6): 062515. arXiv:1703.04250. Bibcode:2017PhRvA..95f2515D. doi:10.1103/PhysRevA.95.062515. S2CID 118956691.
  58. ^ Chatt, J. (1979). "Recommendations for the naming of elements of atomic numbers greater than 100". Pure and Applied Chemistry. 51 (2): 381–384. doi:10.1351/pac197951020381.
  59. ^ Haire, Richard G. (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. p. 1724. ISBN 1-4020-3555-1.
  60. ^ a b Malli, G.L. (2006). "Dissociation energy of ekaplutonium fluoride E126F: The first diatomic with molecular spinors consisting of g atomic spinors". The Journal of Chemical Physics. 124 (7): 071102. Bibcode:2006JChPh.124g1102M. doi:10.1063/1.2173233. PMID 16497023.
  61. ^ a b Jacoby, Mitch (2006). "As-yet-unsynthesized superheavy atom should form a stable diatomic molecule with fluorine". Chemical & Engineering News. 84 (10): 19. doi:10.1021/cen-v084n010.p019a.
  62. ^ a b c Fricke, B.; Greiner, W.; Waber, J. T. (1971). "The continuation of the periodic table up to Z = 172. The chemistry of superheavy elements" (PDF). Theoretica Chimica Acta. 21 (3): 235–260. doi:10.1007/BF01172015. S2CID 117157377.
  63. ^ Nefedov, V.I.; Trzhaskovskaya, M.B.; Yarzhemskii, V.G. (2006). "Electronic Configurations and the Periodic Table for Superheavy Elements" (PDF). Doklady Physical Chemistry. 408 (2): 149–151. doi:10.1134/S0012501606060029. ISSN 0012-5016. S2CID 95738861.
  64. ^ Oganessian, YT; et al. (2002). "Element 118: results from the first 249
    Cf
     + 48
    Ca
     experiment"    . Communication of the Joint Institute for Nuclear Research. Archived from the original on 22 July 2011.
  65. ^ "Livermore scientists team with Russia to discover element 118". Livermore press release. 3 December 2006. Archived from the original on 17 October 2011. Retrieved 18 January 2008.
  66. ^ Oganessian, YT; Abdullin, F; Bailey, PD; et al. (2010). "Synthesis of a New Element with Atomic Number Z = 117". Physical Review Letters. 104 (14): 142502. Bibcode:2010PhRvL.104n2502O. doi:10.1103/PhysRevLett.104.142502. PMID 20481935.
  67. ^ Roberto, JB (2015). "Actinide Targets for Super-Heavy Element Research" (PDF). cyclotron.tamu.edu. Texas A & M University. Retrieved 30 October 2018.
  68. ^ Hagino, Kouichi; Hofmann, Sigurd; Miyatake, Hiroari; Nakahara, Hiromichi (2012). "平成23年度 研究業績レビュー（中間レビュー）の実施について" (PDF). www.riken.jp. RIKEN. Archived from the original (PDF) on 30 March 2019. Retrieved 5 May 2017.
  69. ^ a b c Karpov, A; Zagrebaev, V; Greiner, W (2015). "Superheavy Nuclei: which regions of nuclear map are accessible in the nearest studies" (PDF). cyclotron.tamu.edu. Texas A & M University. Retrieved 30 October 2018.
  70. ^ a b Zagrebaev, Karpov & Greiner 2013.
  71. ^ Giardina, G.; Fazio, G.; Mandaglio, G.; Manganaro, M.; Nasirov, A.K.; Romaniuk, M.V.; Saccà, C. (2010). "Expectations and limits to synthesize nuclei with Z ≥ 120". International Journal of Modern Physics E. 19 (5 & 6): 882–893. Bibcode:2010IJMPE..19..882G. doi:10.1142/S0218301310015333.
  72. ^ Rykaczewski, Krzysztof P. (July 2016). "Super Heavy Elements and Nuclei" (PDF). people.nscl.msu.edu. MSU. Retrieved 30 April 2017.
  73. ^ Kuzmina, A.Z.; Adamian, G.G.; Antonenko, N.V.; Scheid, W. (2012). "Influence of proton shell closure on production and identification of new superheavy nuclei". Physical Review C. 85 (1): 014319. Bibcode:2012PhRvC..85a4319K. doi:10.1103/PhysRevC.85.014319.
  74. ^ a b c d e Koura, H. (2011). Decay modes and a limit of existence of nuclei in the superheavy mass region (PDF). 4th International Conference on the Chemistry and Physics of the Transactinide Elements. Retrieved 18 November 2018.
  75. ^ Kratz, J. V. (5 September 2011). The Impact of Superheavy Elements on the Chemical and Physical Sciences (PDF). 4th International Conference on the Chemistry and Physics of the Transactinide Elements. Retrieved 27 August 2013.
  76. ^ Considine, Glenn D.; Kulik, Peter H. (2002). Van Nostrand's scientific encyclopedia (9 ed.). Wiley-Interscience. ISBN 978-0-471-33230-5. OCLC 223349096.
  77. ^ a b c Koura, H.; Chiba, S. (2013). "Single-Particle Levels of Spherical Nuclei in the Superheavy and Extremely Superheavy Mass Region". Journal of the Physical Society of Japan. 82 (1): 014201. Bibcode:2013JPSJ...82a4201K. doi:10.7566/JPSJ.82.014201.
  78. ^ a b Palenzuela, Y. M.; Ruiz, L. F.; Karpov, A.; Greiner, W. (2012). "Systematic Study of Decay Properties of Heaviest Elements" (PDF). Bulletin of the Russian Academy of Sciences: Physics. 76 (11): 1165–1171. Bibcode:2012BRASP..76.1165P. doi:10.3103/S1062873812110172. ISSN 1062-8738. S2CID 255424602.
  79. ^ Maly, J.; Walz, D.R. (1980). "Search for superheavy elements among fossil fission tracks in zircon" (PDF).
  80. ^ a b Santhosh, K.P.; Priyanka, B.; Nithya, C. (2016). "Feasibility of observing the α decay chains from isotopes of SHN with Z = 128, Z = 126, Z = 124 and Z = 122". Nuclear Physics A. 955 (November 2016): 156–180. arXiv:1609.05498. Bibcode:2016NuPhA.955..156S. doi:10.1016/j.nuclphysa.2016.06.010. S2CID 119219218.
  81. ^ Chowdhury, R. P.; Samanta, C.; Basu, D.N. (2008). "Nuclear half-lives for α -radioactivity of elements with 100 ≤ Z ≤ 130". Atomic Data and Nuclear Data Tables. 94 (6): 781–806. arXiv:0802.4161. Bibcode:2008ADNDT..94..781C. doi:10.1016/j.adt.2008.01.003. S2CID 96718440.
  82. ^ a b Okunev, V.S. (2018). "About islands of stability and limiting mass of the atomic nuclei". IOP Conference Series: Materials Science and Engineering. 468: 012012-1–012012-13. doi:10.1088/1757-899X/468/1/012012.
  83. ^ Dvorak, J.; et al. (2006). "Doubly Magic Nucleus 270
    108    Hs
    162    "    . Physical Review Letters. 97 (24): 242501. Bibcode:2006PhRvL..97x2501D. doi:10.1103/PhysRevLett.97.242501. PMID 17280272.
  84. ^ Seaborg (c. 2006). "transuranium element (chemical element)". Encyclopædia Britannica. Retrieved 2010-03-16.
  85. ^ a b Hoffman, Darleane C.; Lee, Diana M.; Pershina, Valeria (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 1-4020-3555-1. Retrieved 15 July 2023.
  86. ^ Umemoto, Koichiro; Saito, Susumu (1996). "Electronic Configurations of Superheavy Elements". Journal of the Physical Society of Japan. 65 (10): 3175–9. Bibcode:1996JPSJ...65.3175U. doi:10.1143/JPSJ.65.3175. Retrieved 31 January 2021.
  87. ^ Malli, G.L. (2007). "Thirty years of relativistic self-consistent field theory for molecules: relativistic and electron correlation effects for atomic and molecular systems of transactinide superheavy elements up to ekaplutonium E126 with g-atomic spinors in the ground state configuration". Theoretical Chemistry Accounts. 118 (3): 473–482. doi:10.1007/s00214-007-0335-1. S2CID 121566759.

Bibliography

edit
Retrieved from "https://en.wikipedia.org/w/index.php?title=Unbihexium&oldid=1253640444"