Spectral resolution

The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by $\Delta \lambda$ , and is closely related to the resolving power of the spectrograph, defined as $R={\frac {\lambda }{\Delta \lambda }},$ where $\Delta \lambda$ is the smallest difference in wavelengths that can be distinguished at a wavelength of $\lambda$ . For example, the Space Telescope Imaging Spectrograph (STIS) can distinguish features 0.17 nm apart at a wavelength of 1000 nm, giving it a resolution of 0.17 nm and a resolving power of about 5,900. An example of a high resolution spectrograph is the Cryogenic High-Resolution IR Echelle Spectrograph (CRIRES+) installed at ESO's Very Large Telescope, which has a spectral resolving power of up to 100,000.^[1]

Doppler effect

The spectral resolution can also be expressed in terms of physical quantities, such as velocity; then it describes the difference between velocities $\Delta v$ that can be distinguished through the Doppler effect. Then, the resolution is $\Delta v$ and the resolving power is $R={\frac {c}{\Delta v}},$ where $c$ is the speed of light. The STIS example above then has a spectral resolution of 51 km/s.

IUPAC definition

IUPAC defines resolution in optical spectroscopy as the minimum wavenumber, wavelength or frequency difference between two lines in a spectrum that can be distinguished.^[2] Resolving power, R, is given by the transition wavenumber, wavelength or frequency, divided by the resolution.^[3]

References

^ - CRIRES Instrument page at ESO
^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "resolution in optical spectroscopy". doi:10.1351/goldbook.R05319
^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "resolving power, R, in optical spectroscopy". doi:10.1351/goldbook.R05322

Spectral resolution

Contents

Doppler effect

IUPAC definition

See also

References

Further reading