Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.[2]
Clinozoisite | |
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General | |
Category | Sorosilicates Epidote group |
Formula (repeating unit) | Ca2Al3(Si2O7)(SiO4)O(OH) |
IMA symbol | Czo[1] |
Strunz classification | 9.BG.05a |
Dana classification | 58.2.1a.4 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/m |
Unit cell | a = 8.879, b = 5.583 c = 10.155 [Å]; β = 115.50°; Z = 2 |
Identification | |
Color | Colorless, green, gray, light green, yellow green, pink |
Crystal habit | Elongated primatic crystals, striated; granular to fibrous |
Twinning | Lamellar on {100} uncommon |
Cleavage | Perfect on {001} |
Fracture | Irregular/uneven |
Tenacity | Brittle |
Mohs scale hardness | 6–7 |
Luster | Vitreous |
Streak | Grayish white |
Diaphaneity | Transparent to translucent |
Specific gravity | 3.3–3.4 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.706 – 1.724 nβ = 1.708 – 1.729 nγ = 1.712 – 1.735 |
Birefringence | δ = 0.006 – 0.011 |
2V angle | 14 to 90° measured |
References | [2][3][4] |
Clinothulite is a manganese bearing variety with a pinkish hue due to substitution of Mn(III) in the aluminium site.[5]
It was originally discovered in 1896 in East Tyrol, Austria, and is so-named because of its resemblance to zoisite and its monoclinic crystal structure.[2]
It occurs in rocks which have undergone low to medium grade regional metamorphism and in contact metamorphism of high calcium sedimentary rocks. It also occurs in saussurite alteration of plagioclase.[3]
Jadeite bearing pyroxene minerals have suggested clinozoisite and paragonite are associated and derived from lawsonite releasing quartz and water via the following reaction:[6]
References
edit- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ a b c Clinozoisite on Mindat.org
- ^ a b "Clinozoisite in the Handbook of Mineralogy" (PDF). Archived from the original (PDF) on 2015-09-24. Retrieved 2014-03-24.
- ^ Clinozoisite data on Webmineral
- ^ Clinothulite on Mindat
- ^ Deer, William A. (1997). Single-chain Silicates, Volume 2A. Geological Society of London. p. 477.
- Nesse, William D., "Introduction to Mineralogy," (c)2000 Oxford University Press ISBN 0-19-510691-1