Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands. (Q55003871)

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20 March 2020

title

Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands (English)

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20 March 2020

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Friedrich Matthias Bickelhaupt

20 March 2020

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20 March 2020

Florian Hering

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20 March 2020

Jörn Nitsch

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20 March 2020

Ursula Paul

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20 March 2020

Udo Radius

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20 March 2020

publication date

3 December 2014

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20 March 2020

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20 March 2020

volume

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20 March 2020

issue

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20 March 2020

page(s)

1426-1432

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The activation strain model and molecular orbital theory: understanding and designing chemical reactions

20 March 2020

cites work

1 reference

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Nonlinear d(10)-ML2 Transition-Metal Complexes.

16 June 2018

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Synthesis and application of water-soluble NHC transition-metal complexes

16 June 2018

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N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media

16 June 2018

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Metal-catalyzed alpha-arylation of carbonyl and related molecules: novel trends in C-C bond formation by C-H bond functionalization

16 June 2018

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Heterocyclic carbenes: synthesis and coordination chemistry.

16 June 2018

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Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex

16 June 2018

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Theoretical methods of potential use for studies of inorganic reaction mechanisms

16 June 2018

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Catalytic C-h/olefin coupling

16 June 2018

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Bis-NHC chelate complexes of nickel(0) and platinum(0).

16 June 2018

1 reference

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Synthesis of palladium(0) and -(II) complexes with chelating bis(N-heterocyclic carbene) ligands and their application in semihydrogenation

13 August 2018

1 reference

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Facile C-S, S-H, and S-S bond cleavage using a nickel(0) NHC complex

13 August 2018

1 reference

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A general synthetic route to mixed NHC-phosphane palladium(0) complexes (NHC=N-heterocyclic carbene).

13 August 2018

1 reference

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C-F activation of fluorinated arenes using NHC-stabilized nickel(0) complexes: selectivity and mechanistic investigations

13 August 2018

1 reference

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Unusual nickel-mediated C-S cleavage of alkyl and aryl sulfoxides.

13 August 2018

1 reference

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Efficient nickel mediated carbon-carbon bond cleavage of organonitriles.

13 August 2018

1 reference

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Fixation of both O2 and CO2 from air by a crystalline palladium complex bearing N-heterocyclic carbene ligands

13 August 2018

1 reference

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N-Heterocyclic Carbenes in Late Transition Metal Catalysis

13 August 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

The Measure of All Rings-N-Heterocyclic Carbenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

A method for the synthesis of nickel(0) bis(carbene) complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

Low-Coordinate Carbene Complexes of Nickel(0) and Platinum(0)

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

Metal Vapor Synthesis as a Straightforward Route to Group 10 Homoleptic Carbene Complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation

21 January 2018

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An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC4SC02998D

The nature of the bonding in transition-metal compounds

21 January 2018

1 reference

12 December 2020

Choice of coordination number in d10 complexes of group 11 metals

1 reference

12 December 2020

Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0)

1 reference

12 December 2020

Catalytic C-C bond formation accomplished by selective C-F activation of perfluorinated arenes

1 reference

12 December 2020

Transition metal-catalyzed direct arylation of substrates with activated sp3-hybridized C-H bonds and some of their synthetic equivalents with aryl halides and pseudohalides

1 reference

12 December 2020

N-heterocyclic carbenes: a new concept in organometallic catalysis

1 reference

12 December 2020

A defined N-heterocyclic carbene complex for the palladium-catalyzed Suzuki cross-coupling of aryl chlorides at ambient temperatures

1 reference

12 December 2020

Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(ii)–dimethyl moiety

1 reference

12 December 2020

Late-transition-metal complexes as tunable Lewis bases

1 reference

12 December 2020

Si-H activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes

1 reference

12 December 2020

Chemistry of iron N-heterocyclic carbene complexes: syntheses, structures, reactivities, and catalytic applications

1 reference

12 December 2020

Si-H bond activation at {(NHC)₂Ni⁰} leading to hydrido silyl and bis(silyl) complexes: a versatile tool for catalytic Si-H/D exchange, acceptorless dehydrogenative coupling of hydrosilanes, and hydrogenation of disilanes to hydrosilanes

1 reference

12 December 2020

New Concepts for Designing d10-M(L)nCatalysts: d Regime, s Regime and Intrinsic Bite-Angle Flexibility

1 reference

12 December 2020

Identifiers

DOI

10.1039/C4SC02998D

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:29560231%20AND%20SRC:MED&resulttype=core&format=json

20 March 2020

1 reference

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20 March 2020

PubMed publication ID

29560231

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:29560231%20AND%20SRC:MED&resulttype=core&format=json