Flow chemistry as a discovery tool to access sp2-sp3 cross-coupling reactions via diazo compounds. (Q55008995)

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20 March 2020

title

Flow chemistry as a discovery tool to access sp2-sp3 cross-coupling reactions via diazo compounds (English)

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20 March 2020

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20 March 2020

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20 March 2020

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20 March 2020

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20 March 2020

Joel M Hawkins

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20 March 2020

publication date

7 November 2014

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20 March 2020

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20 March 2020

volume

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20 March 2020

issue

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20 March 2020

page(s)

1120-1125

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Controlled multistep synthesis in a three-phase droplet reactor

20 March 2020

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Flow chemistry syntheses of natural products

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Continuous-Flow Synthesis of the Anti-Malaria Drug Artemisinin

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Deciding whether to go with the flow: evaluating the merits of flow reactors for synthesis

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To protonate or alkylate? Stereoselective Brønsted acid catalysis of C-C bond formation using diazoalkanes.

16 June 2018

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New Syntheses of Diazo Compounds

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Synthesis of α-aryl esters and nitriles: deaminative coupling of α-aminoesters and α-aminoacetonitriles with arylboronic acids.

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Continuous-flow synthesis of functionalized phenols by aerobic oxidation of Grignard reagents

13 August 2018

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Metal-free coupling of saturated heterocyclic sulfonylhydrazones with boronic acids

13 August 2018

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Continuous flow generation and reactions of anhydrous diazomethane using a Teflon AF-2400 tube-in-tube reactor.

13 August 2018

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Heating under high-frequency inductive conditions: application to the continuous synthesis of the neurolepticum olanzapine (Zyprexa).

13 August 2018

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Synthesis of acyclic ketones by catalytic, bidirectional homologation of formaldehyde with nonstabilized diazoalkanes. Application of a chiral diazomethyl(pyrrolidine) in total syntheses of erythroxylon alkaloids

13 August 2018

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On being green: can flow chemistry help?

13 August 2018

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Continuous in situ generation, separation, and reaction of diazomethane in a dual-channel microreactor.

13 August 2018

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A flow-microreactor approach to protecting-group-free synthesis using organolithium compounds

13 August 2018

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Metal-free carbon–carbon bond-forming reductive coupling between boronic acids and tosylhydrazones

13 August 2018

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13 August 2018

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13 August 2018

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Catalytic cyclopropanation of alkenes using diazo compounds generated in situ. A novel route to 2-arylcyclopropylamines

13 August 2018

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Flow Chemistry Meets Advanced Functional Materials

13 August 2018

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Preparation of Unsymmetrical Ketones from Tosylhydrazones and Aromatic Aldehydes via Formyl C–H Bond Insertion

21 January 2018

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Development of a Continuous Process for the Industrial Generation of Diazomethane1

21 January 2018

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Safe and Reliable Synthesis of Diazoketones and Quinoxalines in a Continuous Flow Reactor

21 January 2018

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Mild and Selective Heterogeneous Catalytic Hydration of Nitriles to Amides by Flowing through Manganese Dioxide

21 January 2018

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The rapid synthesis of oxazolines and their heterogeneous oxidation to oxazoles under flow conditions

21 January 2018

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A prototype device for evaporation in batch and flow chemical processes

21 January 2018

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Accelerating Spirocyclic Polyketide Synthesis using Flow Chemistry

21 January 2018

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Asymmetric Homogeneous Hydrogenation in Flow using a Tube-in-Tube Reactor

21 January 2018

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Flow synthesis using gaseous ammonia in a Teflon AF-2400 tube-in-tube reactor: Paal–Knorr pyrrole formation and gas concentration measurement by inline flow titration

21 January 2018

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Flow Chemistry Syntheses of Styrenes, Unsymmetrical Stilbenes and Branched Aldehydes

21 January 2018

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A General Continuous Flow Method for Palladium Catalysed Carbonylation Reactions Using Single and Multiple Tube-in-Tube Gas-Liquid Microreactors

21 January 2018

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Scalable in Situ Diazomethane Generation in Continuous-Flow Reactors

21 January 2018

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A selective method for the direct conversion of aldehydes into .beta.-keto esters with ethyl diazoacetate catalyzed by tin(II) chloride

21 January 2018

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Continuous Production of the Diazomethane PrecursorN-Methyl-N-nitroso-p-toluenesulfonamide: Batch Optimization and Transfer into a Microreactor Setup

21 January 2018

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Diazo preparation via dehydrogenation of hydrazones with "activated" DMSO

21 January 2018

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12 December 2020

Enantioselective synthesis of trifluoromethyl-substituted cyclopropanes

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12 December 2020

Arylation and vinylation of alpha-diazocarbonyl compounds with boroxines

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12 December 2020

In situ generation of zinc carbenoids from diazo compounds and zinc salts: asymmetric synthesis of 1,2,3-substituted cyclopropanes

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12 December 2020

The Oxygen-Mediated Synthesis of 1,3-Butadiynes in Continuous Flow: Using Teflon AF-2400 to Effect Gas/Liquid Contact

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12 December 2020

Application of Barluenga Boronic Coupling (BBC) to the Parallel Synthesis of Drug‐like and Drug Fragment‐like Molecules

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12 December 2020

Titration of nonstabilized diazoalkane solutions by fluorine NMR

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12 December 2020

Iron-Catalyzed Cyclopropanation in 6 M KOH with in Situ Generation of Diazomethane

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12 December 2020

Olefination of carbonyl compounds through reductive coupling of alkenylboronic acids and tosylhydrazones

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12 December 2020

Identifiers

DOI

10.1039/C4SC03072A

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:29560199%20AND%20SRC:MED&resulttype=core&format=json

20 March 2020

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20 March 2020

PubMed publication ID

29560199

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