Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols (Q42544898)

2 November 2017

Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols (English)

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2 November 2017

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2 November 2017

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2 November 2017

Yusuke Arai

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2 November 2017

Ren Tomita

series ordinal

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2 November 2017

Gaku Ando

series ordinal

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2 November 2017

language of work or name

English

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publication date

7 December 2015

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Chemistry—A European Journal

2 November 2017

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2 November 2017

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2 November 2017

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2 November 2017

1262-1265

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Recent developments in the trifluoromethylation of alkynes

2 November 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Trifluoromethylation of alkenes with concomitant introduction of additional functional groups.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Addition of CF3 across unsaturated moieties: a powerful functionalization tool

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Fluorinated sulfoximines: syntheses, properties and applications

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Introduction of fluorine and fluorine-containing functional groups.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Intermolecular aminotrifluoromethylation of alkenes by visible-light-driven photoredox catalysis.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Practical and innate carbon-hydrogen functionalization of heterocycles

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Three-component oxytrifluoromethylation of alkenes: highly efficient and regioselective difunctionalization of C=C bonds mediated by photoredox catalysts

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

A "Renaissance" in radical trifluoromethylation

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Copper-mediated difluoromethylation of aryl and vinyl iodides

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Transition metal catalysis and nucleophilic fluorination

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

A new reagent for direct difluoromethylation

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Visible light photocatalysis as a greener approach to photochemical synthesis

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Visible light photoredox catalysis: applications in organic synthesis

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Selective difluoromethylation and monofluoromethylation reactions

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

The many roles for fluorine in medicinal chemistry

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Fluorine in pharmaceuticals: looking beyond intuition

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Electrophilic Perfluoroalkylating Agents

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes.

28 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

A novel visible light mediated radical cyclization of enol lactones: a concise method for fluorinated polycyclic lactone scaffolds

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Visible-light-mediated radical aryldifluoroacetylation of alkynes with ethyl bromodifluoroacetate for the synthesis of 3-difluoroacetylated coumarins.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Selective difluoroalkylation of alkenes by using visible light photoredox catalysis.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Palladium-catalyzed insertion of an allene into an aminal: aminomethylamination of allenes by C-N bond activation

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Nucleophilic difluoromethylation of epoxides with PhSO(NTBS)CF₂H by a preorganization strategy.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

The photocatalyzed Meerwein arylation: classic reaction of aryl diazonium salts in a new light

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and sulfides

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4737308

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

16 August 2018

1 reference

Crossref

https://api.crossref.org/works/10.1002%2FCHEM.201504838

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

21 January 2018

1 reference

Crossref

https://api.crossref.org/works/10.1002%2FCHEM.201504838

Copper-Catalyzed Direct C-2 Difluoromethylation of Furans and Benzofurans: Access to C-2 CF2H Derivatives

21 January 2018

1 reference

Crossref

https://api.crossref.org/works/10.1002%2FCHEM.201504838

A remarkably efficient fluoroalkylation of cyclic sulfates and sulfamidates with PhSO2CF2H: facile entry into beta-difluoromethylated or beta-difluoromethylenated alcohols and amines

21 January 2018

1 reference

12 December 2020

Visible-light photoredox catalysis

1 reference

12 December 2020

Facile synthesis of chiral alpha-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines

1 reference

12 December 2020

Chloro, difluoromethylation and chloro, carbomethoxydifluoromethylation: reaction of radicals derived from RfSO2Cl with unactivated alkenes under metal-free conditions

1 reference

12 December 2020

A New Method for Aromatic Difluoromethylation: Copper-Catalyzed Cross-Coupling and Decarboxylation Sequence from Aryl Iodides

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12 December 2020

Combining photoredox-catalyzed trifluoromethylation and oxidation with DMSO: facile synthesis of α-trifluoromethylated ketones from aromatic alkenes

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12 December 2020

Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates

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12 December 2020

Copper- and iron-catalyzed decarboxylative tri- and difluoromethylation of α,β-unsaturated carboxylic acids with CF3SO2Na and (CF2HSO2)2Zn via a radical process

1 reference

12 December 2020

Direct α-siladifluoromethylation of lithium enolates with Ruppert-Prakash reagent via C-F bond activation

1 reference

12 December 2020

N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: a new difluoromethylation reagent for S-, N-, and C-nucleophiles

1 reference

12 December 2020

Fluoroalkylative aryl migration of conjugated N-arylsulfonylated amides using easily accessible sodium di- and monofluoroalkanesulfinates

1 reference

12 December 2020

Photoredox-catalyzed tandem radical cyclization of N-arylacrylamides: general methods to construct fluorinated 3,3-disubstituted 2-oxindoles using fluoroalkylsulfonyl chlorides

1 reference

12 December 2020

A practical source of chlorodifluoromethyl radicals. Convergent routes to gem-difluoroalkenes and -dienes and (2,2-difluoroethyl)-indoles, -azaindoles, and -naphthols

1 reference

12 December 2020

Sandmeyer difluoromethylation of (hetero-)arenediazonium salts

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12 December 2020

Electrophilic trifluoromethylation by use of hypervalent iodine reagents

1 reference

12 December 2020

Efficient Cu-catalyzed atom transfer radical addition reactions of fluoroalkylsulfonyl chlorides with electron-deficient alkenes induced by visible light

1 reference

12 December 2020

Aromatic trifluoromethylation with metal complexes

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12 December 2020

Difluoromethylene phosphabetaine as an equivalent of difluoromethyl carbanion

1 reference

12 December 2020

Photoredox-Catalyzed Intramolecular Aminodifluoromethylation of Unactivated Alkenes

1 reference

12 December 2020

Copper-catalyzed difluoromethylation of β,γ-unsaturated carboxylic acids: an efficient allylic difluoromethylation

1 reference

12 December 2020

S-((phenylsulfonyl)difluoromethyl)thiophenium salts: carbon-selective electrophilic difluoromethylation of β-ketoesters, β-diketones, and dicyanoalkylidenes

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12 December 2020

Pd(0)-Catalyzed radical aryldifluoromethylation of activated alkenes

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12 December 2020

Umpolung of fluoroform by C-F bond activation: direct difluoromethylation of lithium enolates

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12 December 2020

Good partnership between sulfur and fluorine: sulfur-based fluorination and fluoroalkylation reagents for organic synthesis

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12 December 2020

Highly regio- and diastereoselective synthesis of CF3-substituted lactones via photoredox-catalyzed carbolactonization of alkenoic acids

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12 December 2020

Identifiers

DOI

10.1002/CHEM.201504838

1 reference

release_gccd4m5ecvarnopga4yxhe6niq

2 November 2017

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Fatcat

https://api.fatcat.wiki/v0/release/gccd4m5ecvarnopga4yxhe6niq

24 November 2022

mapped directly with Wikidata item

1 reference

2 November 2017

PubMed publication ID

26639021

1 reference