Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions (Q46684474)

24 December 2017

http://europepmc.org/abstract/MED/26273792

title

Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions (English)

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24 December 2017

http://europepmc.org/abstract/MED/26273792

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31 May 2020

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31 May 2020

Bin Wang

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31 May 2020

Mi Sook Seo

series ordinal

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31 May 2020

language of work or name

English

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publication date

13 August 2015

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24 December 2017

http://europepmc.org/abstract/MED/26273792

published in

Angewandte Chemie International Edition

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31 May 2020

volume

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issue

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31 May 2020

page(s)

11740-11744

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Non-heme Fe(IV)-oxo intermediates

31 May 2020

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Epoxidation of olefins by cytochrome P450: Evidence from site-specific mutagenesis for hydroperoxo-iron as an electrophilic oxidant

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Multiple active oxidants in competitive epoxidations catalyzed by porphyrins and corroles

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Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: evidence for a "third oxidant" in high-valent porphyrinoid oxidations

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Substrate modulation of the properties and reactivity of the oxy-ferrous and hydroperoxo-ferric intermediates of cytochrome P450cam as shown by cryoreduction-EPR/ENDOR spectroscopy

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Oxoiron(IV) porphyrin pi-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions

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Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III)-hydroperoxo species is a sluggish oxidant.

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Searching for the second oxidant in the catalytic cycle of cytochrome P450: a theoretical investigation of the iron(III)-hydroperoxo species and its epoxidation pathways

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A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions.

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Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.

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Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates

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Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

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21 January 2018

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Iron Catalyzed Competitive Olefin Oxidation and ipso-Hydroxylation of Benzoic Acids: Further Evidence for an FeV═O Oxidant

21 January 2018

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Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

21 January 2018

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Gauging the Relative Oxidative Powers of Compound I, Ferric-Hydroperoxide, and the Ferric-Hydrogen Peroxide Species of Cytochrome P450 Toward C−H Hydroxylation of a Radical Clock Substrate

21 January 2018

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21 January 2018

Identifiers

DOI

10.1002/ANIE.201505796

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:26273792%20AND%20SRC:MED&resulttype=core&format=json

31 May 2020

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:26273792%20AND%20SRC:MED&resulttype=core&format=json