Synthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes (Q33755592)

29 July 2017

title

Synthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes (English)

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29 July 2017

Baoguo Zhao

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29 July 2017

Haifeng Du

series ordinal

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29 July 2017

Sunliang Cui

series ordinal

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29 July 2017

Yian Shi

series ordinal

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29 July 2017

language of work or name

English

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publication date

1 March 2010

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Journal of the American Chemical Society

29 July 2017

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inferred from page(s)

published in

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29 July 2017

volume

132

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29 July 2017

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29 July 2017

page(s)

3523-3532

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Metal-catalysed 1,2-diamination reactions

29 July 2017

cites work

1 reference

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Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes

21 June 2018

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Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium

21 June 2018

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Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter

21 June 2018

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Cu(I)-catalyzed diamination of disubstituted terminal olefins: an approach to potent NK1 antagonist

21 June 2018

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Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex

21 June 2018

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A palladium-catalyzed dehydrogenative diamination of terminal olefins

21 June 2018

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Insights into directing group ability in palladium-catalyzed C-H bond functionalization

21 June 2018

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Cu(I)-catalyzed asymmetric diamination of conjugated dienes

21 June 2018

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Organocatalytic oxidation. Asymmetric epoxidation of olefins catalyzed by chiral ketones and iminium salts

21 June 2018

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Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation

21 June 2018

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Mechanisms of catalyst poisoning in palladium-catalyzed cyanation of haloarenes. remarkably facile C-N bond activation in the [(Ph3P)4Pd]/[Bu4N]+ CN- system.

21 June 2018

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Copper(II) carboxylate promoted intramolecular diamination of terminal alkenes: improved reaction conditions and expanded substrate scope

21 June 2018

1 reference

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Reactions of hypervalent iodine reagents with palladium: mechanisms and applications in organic synthesis

21 June 2018

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A new synthesis of imidazolidin-2-ones via Pd-catalyzed carboamination of N-allylureas

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Intramolecular Pd-catalyzed carboetherification and carboamination. Influence of catalyst structure on reaction mechanism and product stereochemistry

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Vicinal diamino functionalities as privileged structural elements in biologically active compounds and exploitation of their synthetic chemistry

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Reaction progress kinetic analysis: a powerful methodology for mechanistic studies of complex catalytic reactions

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Elucidating the significance of beta-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Metal-Initiated Amination of Alkenes and Alkynes

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Gold(I)-catalyzed intramolecular dihydroamination of allenes with N,N'-disubstituted ureas to form bicyclic imidazolidin-2-ones

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Synthesis of beta-, gamma-, and delta-lactams via Pd(II)-catalyzed C-H activation reactions

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

An advance on exploring N-tert-butanesulfinyl imines in asymmetric synthesis of chiral amines

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Mechanistic studies of a palladium-catalyzed intramolecular hydroamination of unactivated alkenes: protonolysis of a stable palladium alkyl complex is the turnover-limiting step

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Catalytic diamination of alkenes using N,N-dibromo-p-toluenesulfonamide as electrophile and nitriles as nucleophiles

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Highly selective C-H functionalization/halogenation of acetanilide.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Copper(II) acetate promoted intramolecular diamination of unactivated olefins

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Aerobic oxidative amination of unactivated alkenes catalyzed by palladium

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Asymmetric allylic alkylation, an enabling methodology

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

A highly selective catalytic method for the oxidative functionalization of C-H bonds

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Insights into the Origin of High Activity and Stability of Catalysts Derived from Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C−N Bond Formation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex: relevance to catalytic amination

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Electrophilic diamination of alkenes by using FeCl(3)-PPh(3) complex as the catalyst

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Observation of unusual kinetics in Heck reactions of aryl halides: the role of non-steady-state catalyst concentration

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Kinetic and density functional studies on alkyl-carbene elimination from Pd(II) heterocylic carbene complexes: a new type of reductive elimination with clear implications for catalysis

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Kinetic studies of Heck coupling reactions using palladacycle catalysts: experimental and kinetic modeling of the role of dimer species

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Palladium-Catalyzed Diamination of Unactivated Alkenes UsingN-Fluorobenzenesulfonimide as Source of Electrophilic Nitrogen

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2846102

Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions

10 December 2018

1 reference

12 December 2020

Ritter-type reactions of N-chlorosaccharin: a method for the electrophilic diamination of alkenes

1 reference

12 December 2020

Palladium-catalyzed synthesis of N-aryl pyrrolidines from gamma-(N-Arylamino) alkenes: evidence for chemoselective alkene insertion into Pd--N bonds

1 reference

12 December 2020

Organocatalytic asymmetric epoxidation of olefins by chiral ketones

1 reference

12 December 2020

Palladium-catalyzed ring-forming aminoacetoxylation of alkenes

1 reference

12 December 2020

Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation

1 reference

12 December 2020

Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP)

1 reference

12 December 2020

Dramatic acceleration of the pd-catalyzed [4+2] benzannulation reaction of enynes and diynes in the presence of lewis acids and bases: expanded scope and new mechanistic insights

1 reference

12 December 2020

Palladium-Catalyzed Oxidation ofBoc-ProtectedN-Methylamines with IOAc as the Oxidant: ABoc-Directed sp3C−H Bond Activation

1 reference

12 December 2020

A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes

1 reference

12 December 2020

A Pd(0)-catalyzed diamination of terminal olefins at allylic and homoallylic carbons via formal C-H activation under solvent-free conditions

1 reference

12 December 2020

A mild Cu(I)-catalyzed regioselective diamination of conjugated dienes

1 reference

12 December 2020

Exploring the nickel-catalyzed oxidation of alkenes: a diamination by sulfamide transfer

1 reference

12 December 2020

Catalytic asymmetric diamination of conjugated dienes and triene

1 reference

12 December 2020

Cu(I)-catalyzed intermolecular diamination of activated terminal olefins

1 reference

12 December 2020

Advancing palladium-catalyzed C-N bond formation: bisindoline construction from successive amide transfer to internal alkenes

1 reference

12 December 2020

Oxidative diamination of alkenes with ureas as nitrogen sources: mechanistic pathways in the presence of a high oxidation state palladium catalyst

1 reference

12 December 2020

Chiral tertiary diamines in asymmetric synthesis

1 reference

12 December 2020

Cu(I)-catalyzed cycloguanidination of olefins

1 reference

12 December 2020

Intramolecular diamination of alkenes with palladium(II)/copper(II) bromide and IPy2BF4: the role of halogenated intermediates

1 reference

12 December 2020

Carbon-fluorine reductive elimination from a high-valent palladium fluoride

1 reference

12 December 2020

Synthesis of diamino carboxylic esters by palladium-catalyzed oxidative intramolecular diamination of acrylates

1 reference

12 December 2020

Transition-metal-catalyzed diamination of olefins

1 reference

12 December 2020

On the Pd-catalyzed vinylation of aryl halides with tris(alkoxy)vinylsilanes in water

1 reference

12 December 2020

The Chemistry of Vicinal Diamines

1 reference

12 December 2020

A Novel Electrophilic Diamination Reaction of Alkenes

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12 December 2020

Identifiers

DOI

10.1021/JA909459H

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29 July 2017

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29 July 2017

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