Recent advances in enantioselective copper-catalyzed 1,4-addition (Q37473046)

20 August 2017

title

Recent advances in enantioselective copper-catalyzed 1,4-addition (English)

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20 August 2017

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Ben L Feringa

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Adriaan Jacobus Minnaard

series ordinal

object named as

Adriaan J Minnaard

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20 August 2017

Thomas Jerphagnon

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20 August 2017

M Gabriella Pizzuti

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20 August 2017

publication date

11 February 2009

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20 August 2017

published in

Chemical Society Reviews

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20 August 2017

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20 August 2017

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20 August 2017

page(s)

1039-1075

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Tandem one pot asymmetric conjugate addition-vinyl triflate formation-cross coupling methodology

20 August 2017

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Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions

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Modular peptide-based phosphine ligands in asymmetric catalysis: efficient and enantioselective Cu-catalyzed conjugate additions to five-, six-, and seven-membered cyclic enones

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Catalytic enantioselective synthesis of prostaglandin E(1) methyl ester using a tandem 1,4-addition-aldol reaction to a cyclopenten-3,5-dione monoacetal

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Highly Enantioselective Copper-Phosphoramidite Catalyzed Kinetic Resolution of Chiral 2-Cyclohexenones This work was supported by the Dutch Foundation for Scientific Research (NWO)

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beta-Peptides: from structure to function

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A convergent synthesis of (+)-cryptophycin B, a potent antitumor macrolide from Nostoc sp. cyanobacteria

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Catalytic asymmetric conjugate addition of dialkylzinc reagents to beta-aryl-alpha,beta-unsaturated N-2,4,6-triisopropylphenylsulfonylaldimines with use of N-Boc-L-Val-connected amidophosphane-copper(I) catalyst

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1,4-Addition of Diethylzinc to Cyclohexenone Catalyzed by CuOTf-Sulfonamide Combined System. Evidence Supporting a Concerted Mechanism

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Highly Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones with Fine-Tunable Phosphite−Pyridine Ligands

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Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds

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Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity

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Copper-catalyzed asymmetric conjugate addition of trialkylaluminium reagents to trisubstituted enones: construction of chiral quaternary centers

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Copper(I) thiolate catalysts in asymmetric conjugate addition reactions

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Enantioselective copper-catalyzed conjugate addition to trisubstituted cyclohexenones: construction of stereogenic quaternary centers

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Synthetic Molecular Motors and Mechanical Machines

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On the use of phosphoramidite ligands in copper-catalyzed asymmetric transformations with trialkylaluminum reagents

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Cu-catalyzed enantioselective conjugate additions of alkyl zinc reagents to unsaturated N-acyloxazolidinones promoted by a chiral triamide phosphane

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Organocopper for the craftsman cunning at his trade

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Readily prepared chiral P,N ligands and their applications in cu-catalyzed enantioselective conjugate additions

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11 October 2022

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Catalytic asymmetric tandem transformations triggered by conjugate additions

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11 October 2022

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Enantioselective Conjugate Addition of Dialkylzinc Reagents to Cyclic and Acyclic Enones Catalyzed by Chiral Copper Complexes of New Phosphorus Amidites

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11 October 2022

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Two birds with one metallic stone: single-pot catalysis of fundamentally different transformations

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A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition

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One-pot asymmetric conjugate addition-trapping of zinc enolates by activated electrophiles

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Copper-catalyzed enantioselective intramolecular conjugate addition/trapping reactions: synthesis of cyclic compounds with multichiral centers

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A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones

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11 October 2022

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Highly Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc to Nitroalkenes

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Copper-catalysed asymmetric conjugate addition of organometallic reagents to enones using S,O-ligands with a xylofuranose backbone

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Biphenol-based phosphoramidite ligands for the enantioselective copper-catalyzed conjugate addition of diethylzinc

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11 October 2022

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Enantioselective synthesis of nitroalkanes bearing all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions

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11 October 2022

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Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using chiral spiro phosphoramidites as ligands

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11 October 2022

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Enantioselective Cu-catalyzed conjugate addition of diethylzinc to acyclic aliphatic enones.

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11 October 2022

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Making molecular machines work

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11 October 2022

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Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to acyclic aliphatic enones

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11 October 2022

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Catalytic asymmetric synthesis of phthioceranic acid, a heptamethyl-branched acid from Mycobacterium tuberculosis

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11 October 2022

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Highly enantioselective conjugate addition of AlMe3 to linear aliphatic enones by a designed catalyst.

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11 October 2022

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Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol

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11 October 2022

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Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters

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11 October 2022

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Thioether–phosphinite and diphosphinite ligands derived from d-xylose for the copper-catalyzed asymmetric 1,4-addition to 2-cyclohexenone

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11 October 2022

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The direct formation of functionalized alkyl(aryl)zinc halides by oxidative addition of highly reactive zinc with organic halides and their reactions with acid chlorides, .alpha.,.beta.-unsaturated ketones, and allylic, aryl, and vinyl halides

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11 October 2022

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Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones in the presence of planar-chiral phosphaferrocene-oxazoline ligands

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11 October 2022

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Catalytic asymmetric synthesis of acyclic arrays by tandem 1,4-addition-aldol reactions

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11 October 2022

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An iterative catalytic route to enantiopure deoxypropionate subunits: asymmetric conjugate addition of grignard reagents to alpha,beta-unsaturated thioesters.

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11 October 2022

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New Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR2to Carbonyl Compounds

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11 October 2022

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Enantioselective total synthesis of erogorgiaene: applications of asymmetric Cu-catalyzed conjugate additions of alkylzincs to acyclic enones

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11 October 2022

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On the Mechanism of the Copper-Catalyzed Enantioselective 1,4-Addition of Grignard Reagents to α,β-Unsaturated Carbonyl Compounds

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11 October 2022

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Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation

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Total synthesis of enantiopure beta-D-mannosyl phosphomycoketides from Mycobacterium tuberculosis

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Copper-catalyzed asymmetric ring opening of oxabicyclic alkenes with Grignard reagents

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Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications

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SimplePhos monodentate ligands: synthesis and application in copper-catalyzed reactions

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Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones

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Cu(I) Tol-BINAP-catalyzed enantioselective Michael reactions of Grignard reagents and unsaturated esters

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Structure Identification of Precatalytic Copper Phosphoramidite Complexes in Solution

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Highly practical and enantioselective cu-catalyzed conjugate addition of alkylzinc reagents to cyclic enones at ambient temperature

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Asymmetric hydrogenation using monodentate phosphoramidite ligands

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Copper-Catalyzed Enantioselective Michael Additions: Recent Progress with New Phosphorus Ligands

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P-chiral o-phosphinophenol as a P/O hybrid ligand: preparation and use in Cu-catalyzed asymmetric conjugate addition of diethylzinc to acyclic enones

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11 October 2022

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Tandem enantioselective conjugate addition--cyclopropanation. Application to natural products synthesis

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Mixed thioether-phosphite and phosphine-phosphite ligands for copper-catalyzed asymmetric 1,4-addition of organometallic reagents to cyclohexenone

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11 October 2022

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Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones

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11 October 2022

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Dramatic improvement of the enantiomeric excess in the asymmetric conjugate addition reaction using new experimental conditions

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11 October 2022

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Copper-catalyzed enantioselective conjugate addition of Grignard reagents to alpha,beta-unsaturated esters

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11 October 2022

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Asymmetric total synthesis of PDIM A: a virulence factor of Mycobacterium tuberculosis

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11 October 2022

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Catalytic enantioselective alkylations of tetrasubstituted olefins. Synthesis of all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to enones

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11 October 2022

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Elucidation of the mechanism of the 1,6-cuprate addition to acceptor-substituted enymes through 13C kinetic isotope effects: experimental and theoretical studies

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11 October 2022

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Cu-catalyzed asymmetric conjugate additions of dialkyl- and diarylzinc reagents to acyclic beta-silyl-alpha,beta-unsaturated ketones. Synthesis of allylsilanes in high diastereo- and enantiomeric purity

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11 October 2022

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Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry

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11 October 2022

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Ueber die Einwirkung von Fettaldehyden auf Malonsäure und Aethylmalonat

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Catalytic asymmetric synthesis of mycocerosic acid

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Highly enantioselective 1,4-addition of diorganozinc reagents to cyclic enones using chiral diphosphite ligands derived from H8-binaphthol

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11 October 2022

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On the role of PIII ligands in the conjugate addition of diorganozinc derivatives to enones

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11 October 2022

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Sugar–phosphite–oxazoline and phosphite–phosphoroamidite ligand libraries for Cu-catalyzed asymmetric 1,4-addition reactions

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11 October 2022

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Cu-catalyzed enantioselective conjugate addition of alkylzincs to cyclic nitroalkenes: catalytic asymmetric synthesis of cyclic alpha-substituted ketones

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11 October 2022

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CD1c presentation of synthetic glycolipid antigens with foreign alkyl branching motifs

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11 October 2022

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Copper-catalyzed enantioselective conjugate addition of grignard reagents to acyclic enones

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11 October 2022

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Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis.

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11 October 2022

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Biologically active Phytophthora mating hormone prepared by catalytic asymmetric total synthesis

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11 October 2022

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Copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted enones. Construction of all-carbon quaternary chiral centers

1 reference

11 October 2022

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The art of building small: from molecular switches to molecular motors

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11 October 2022

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A catalytic and iterative route to beta-substituted esters via highly enantioselective conjugate addition of dimethylzinc to unsaturated malonates

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11 October 2022

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Enantiospecific synthesis of the (9S,18R)-diastereomer of the leukocyte adhesion inhibitor cyclamenol A.

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11 October 2022

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Highly versatile enantioselective conjugate addition of Grignard reagents to alpha,beta-unsaturated thioesters

1 reference

11 October 2022

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Phosphoramidites: marvellous ligands in catalytic asymmetric conjugate addition

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11 October 2022

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Efficient cu-catalyzed asymmetric conjugate additions of alkylzincs to trisubstituted cyclic enones

1 reference

11 October 2022

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Highly enantioselective Cu-catalyzed conjugate additions of dialkylzinc reagents to unsaturated furanones and pyranones: preparation of air-stable and catalytically active Cu-peptide complexes

1 reference

11 October 2022

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Enantioselective conjugate addition of dialkylzinc and diphenylzinc to enones catalyzed by a chiral copper(I) binaphthylthiophosphoramide or binaphthylselenophosphoramide ligand system

1 reference

11 October 2022

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X-Ray, Molecular Diffusion, and NOESY NMR Studies of Chiral, Tetranuclear Cu(I) Catalysts Based on Monodentate Thiol Analogues of TADDOL

1 reference

11 October 2022

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Catalytic enantioselective synthesis of (-)-prostaglandin E1 methyl ester based on a tandem 1,4-addition-aldol reaction

1 reference

11 October 2022

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Asymmetric synthesis of all-carbon benzylic quaternary stereocenters via Cu-catalyzed conjugate addition of dialkylzinc reagents to 5-(1-arylalkylidene) Meldrum's acids

1 reference

11 October 2022

https://opencitations.net/index/coci/api/v1/references/10.1039/B816853A

Unprecedented copper-catalyzed asymmetric conjugate addition of organometallic reagents to alpha,beta-unsaturated lactams

1 reference

11 October 2022

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Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.

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11 October 2022

https://opencitations.net/index/coci/api/v1/references/10.1039/B816853A

Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones

1 reference

11 October 2022

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Aminohydroxyphosphine ligand for the copper-catalyzed enantioselective conjugate addition of organozinc reagents

1 reference

11 October 2022

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Highly enantioselective conjugate addition of dialkylzinc reagents to acyclic nitroalkenes: a catalytic route to beta2-amino acids, aldehydes, and alcohols

1 reference

11 October 2022

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Opening the 'black box': oscillations in organocuprate conjugate addition reactions

1 reference

11 October 2022

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High enantioselectivity is induced by a single monodentate phosphoramidite ligand in iridium-catalyzed asymmetric hydrogenation

1 reference

11 October 2022

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Catalytic asymmetric organozinc additions to carbonyl compounds

1 reference

11 October 2022

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Highly Enantioselective Copper-Phosphoramidite Catalyzed Kinetic Resolution of Chiral 2-Cyclohexenones

1 reference

15 December 2024

https://opencitations.net/index/api/v1/references/10.1039/B816853A

The Iterative Synthesis of Acyclic Deoxypropionate Units and Their Implication in Polyketide-Derived Natural Products

1 reference

15 December 2024

https://opencitations.net/index/api/v1/references/10.1039/B816853A

The constitution of the grignard reagent—II

1 reference

15 December 2024

https://opencitations.net/index/api/v1/references/10.1039/B816853A

Catalytic asymmetric synthesis of enantiopure isoprenoid building blocks: application in the synthesis of apple leafminer pheromones

2 references

15 December 2024

https://opencitations.net/index/api/v1/references/10.1039/B816853A

15 December 2024

https://opencitations.net/index/api/v1/citations/10.1039/B419268K

Identifiers

DOI

10.1039/B816853A

1 reference

20 August 2017

1 reference