Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation (Q57625008)

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scholarly article by Ryuji Imayoshi et al published 5 July 2017 in European Journal of Inorganic Chemistry

Language	Label	Description	Also known as
English	Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation	scholarly article by Ryuji Imayoshi et al published 5 July 2017 in European Journal of Inorganic Chemistry

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scholarly article

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Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation (English)

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Yoshiaki Nishibayashi

5

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Yoshiaki Nishibayashi

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author name string

Ryuji Imayoshi

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Kazunari Nakajima

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Jun Takaya

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Nobuharu Iwasawa

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publication date

5 July 2017

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European Journal of Inorganic Chemistry

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2017

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32

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3769-3778

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Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

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Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

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Dinitrogen binding and cleavage by multinuclear iron complexes

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Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

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Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

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Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals.

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Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

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Metal-Mediated Production of Isocyanates, R3 EN=C=O from Dinitrogen, Carbon Dioxide, and R3 ECl.

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Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states

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Nitrogen fixation revisited on iron(0) dinitrogen phosphine complexes

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N2 activation by an iron complex with a strong electron-donating iminophosphorane ligand.

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Binding of dinitrogen to an iron-sulfur-carbon site

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Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.

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Molybdenum dinitrogen complexes facially coordinated by linear tridentate PEP ligands (E = N or P): impact of the central E donor in trans-position to N2.

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Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes.

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Molybdenum(0) Dinitrogen Complexes Supported by Pentadentate Tetrapodal Phosphine Ligands: Structure, Synthesis, and Reactivity toward Acids.

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Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework.

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Conversion of Dinitrogen into Acetonitrile under Ambient Conditions.

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Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia

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Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides.

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Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand

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An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction

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Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation.

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Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes.

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Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

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Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen.

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Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

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Catalytic reduction of dinitrogen to ammonia at a single molybdenum center.

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Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment

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A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

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Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

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Catalytic formation of ammonia from molecular dinitrogen by use of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing PNP-pincer ligands: remarkable effect of substituent at PNP-pincer ligand.

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Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.

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Catalytic reduction of dinitrogen to ammonia by use of molybdenum-nitride complexes bearing a tridentate triphosphine as catalysts.

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Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands

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Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

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Catalytic conversion of nitrogen to ammonia by an iron model complex

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Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor

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Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.

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A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting State

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Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET.

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Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand.

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Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands.

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Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex.

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Reductive silylation of molecular nitrogen via fixation to tris(trialkylsilyl)amine

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Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

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Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

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Cobalt-catalyzed transformation of molecular dinitrogen into silylamine under ambient reaction conditions

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Vanadium-catalyzed Reduction of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

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Catalytic silylation of dinitrogen with a dicobalt complex

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Silylation of Dinitrogen Catalyzed by Hydridodinitrogentris(Triphenylphosphine)Cobalt(I)

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Dinitrogen Complexes of Sulfur-Ligated Iron

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High-Spin Iron(I) and Iron(0) Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands.

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Dinitrogen complexes supported by tris(phosphino)silyl ligands.

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Zwitterionic stabilization of a reactive cobalt tris-isocyanide monoanion by cation coordination

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Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

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10.1002/EJIC.201700569

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