Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation (Q57625008)

object named as

Yoshiaki Nishibayashi

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author name string

Ryuji Imayoshi

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Kazunari Nakajima

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Jun Takaya

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Nobuharu Iwasawa

European Journal of Inorganic Chemistry

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publication date

5 July 2017

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published in

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volume

2017

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issue

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page(s)

3769-3778

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cites work

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Dinitrogen binding and cleavage by multinuclear iron complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Metal-Mediated Production of Isocyanates, R3 EN=C=O from Dinitrogen, Carbon Dioxide, and R3 ECl.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

A Terminal N2 Complex of High-Spin Iron(I) in a Weak, Trigonal Ligand Field

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Nitrogen fixation revisited on iron(0) dinitrogen phosphine complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

N2 activation by an iron complex with a strong electron-donating iminophosphorane ligand.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Binding of dinitrogen to an iron-sulfur-carbon site

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Molybdenum dinitrogen complexes facially coordinated by linear tridentate PEP ligands (E = N or P): impact of the central E donor in trans-position to N2.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Molybdenum(0) Dinitrogen Complexes Supported by Pentadentate Tetrapodal Phosphine Ligands: Structure, Synthesis, and Reactivity toward Acids.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic formation of ammonia from molecular dinitrogen by use of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing PNP-pincer ligands: remarkable effect of substituent at PNP-pincer ligand.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of dinitrogen to ammonia by use of molybdenum-nitride complexes bearing a tridentate triphosphine as catalysts.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic conversion of nitrogen to ammonia by an iron model complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting State

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Reductive silylation of molecular nitrogen via fixation to tris(trialkylsilyl)amine

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Cobalt-catalyzed transformation of molecular dinitrogen into silylamine under ambient reaction conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Vanadium-catalyzed Reduction of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Catalytic silylation of dinitrogen with a dicobalt complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Silylation of Dinitrogen Catalyzed by Hydridodinitrogentris(Triphenylphosphine)Cobalt(I)

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Room temperature benzene C-H activation by a new [PSiP]Ir pincer complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Rhodium and iridium amido complexes supported by silyl pincer ligation: ammonia N-H bond activation by a [PSiP]Ir complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Synthesis and characterization of five-coordinate, 16-electron Ru(II) complexes supported by tridentate bis(phosphino)silyl ligation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

An unusual example of hypervalent silicon: a five-coordinate silyl group bridging two palladium or nickel centers through a nonsymmetrical four-center two-electron bond

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Understanding the Solution and Solid-State Structures of Pd and Pt PSiP Pincer-Supported Hydrides

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Silanol-based pincer Pt(II) complexes: synthesis, structure, and unusual reactivity.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Si-C bond cleavage by hydride complexes of rhodium and iridium: comparison of Si-C(sp(2)) and Si-C(sp(3)) activation.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

The unusual hydridicity of a cobalt bound Si-H moiety.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Hydrocarboxylation of allenes with CO2 catalyzed by silyl pincer-type palladium complex.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Efficient one-to-one coupling of easily available 1,3-dienes with carbon dioxide

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Use of formate salts as a hydride and a co2 source in PGeP-palladium complex-catalyzed hydrocarboxylation of allenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Reactions of 'pincer' pyridine dicarbene complexes of Fe(0) with silanes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Precursors to dinitrogen reduction: structures and reactivity of trans-[Fe(DMeOPrPE)2(eta(2)-H2)H]+ and trans-[Fe(DMeOPrPE)2(N2)H]+.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Dinitrogen Complexes of Sulfur-Ligated Iron

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

A Nonclassical Dihydrogen Adduct of S = 1/2 Fe(I)

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Selective extraction of N2 from air by diarylimine iron complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

High-Spin Iron(I) and Iron(0) Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

The nature of the active species in bis(imino)pyridyl cobalt ethylene polymerisation catalysts

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Dinitrogen complexes supported by tris(phosphino)silyl ligands.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Zwitterionic stabilization of a reactive cobalt tris-isocyanide monoanion by cation coordination

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Boryl-mediated reversible H2 activation at cobalt: catalytic hydrogenation, dehydrogenation, and transfer hydrogenation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Chemistry of reduced monomeric and dimeric cobalt complexes supported by a PNP pincer ligand.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Evaluating molecular cobalt complexes for the conversion of N2 to NH3

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Monoanionic bis(carbene) pincer complexes featuring cobalt(I-III) oxidation states

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Chemical Redox Agents for Organometallic Chemistry

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

SIR97: a new tool for crystal structure determination and refinement

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

21 January 2018

A short history of SHELX

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Bis[1,2-bis(dimethylphosphino)ethane]dihydrogenhydridoiron(II) tetraphenylborate as a model for the function of nitrogenases

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Synthesis, characterization, and catalytic behavior of a PSiP pincer-type ruthenium(II) complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

Dinitrogen activation upon reduction of a triiron(II) complex

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Protonation studies of a mono-dinitrogen complex of chromium supported by a 12-membered phosphorus macrocycle containing pendant amines

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Nickel and palladium silyl pincer complexes: unusual structural rearrangements that involve reversible Si-C(sp(3)) and Si-C(sp(2)) bond activation

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Four-Coordinate, 14-Electron RuIIComplexes: Unusual Trigonal Pyramidal Geometry Enforced by Bis(phosphino)silyl Ligation

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Mild reduction of carbon dioxide to methane with tertiary silanes catalyzed by platinum and palladium silyl pincer complexes

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Synthesis, structure, and reactivity of hydridoiridium complexes bearing a pincer-type PSiP ligand

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of η2-(Si-H) metal(0) and pentacoordinate silyl metal(II) hydride complexes of the Ni triad bearing a PSiP-pincer ligand

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Efficient synthesis of diborylalkenes from alkenes and diboron by a new PSiP-pincer palladium-catalyzed dehydrogenative borylation

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Two reversible σ-bond metathesis pathways for boron-palladium bond formation: selective synthesis of isomeric five-coordinate borylpalladium complexes

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Silyl ligand mediated reversible β-hydrogen elimination and hydrometalation at palladium

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Influence of thetrans Substituent on N2 Bonding in Iron(ii)-Phosphane Complexes: Structure, Synthesis, and Properties of the Monomeric Adductstrans-[FeXN2(depe)2]BPh4, X=Cl, Br

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Bis(diisopropylphosphino)pyridine iron dicarbonyl, dihydride, and silyl hydride complexes

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Protonation of ferrous dinitrogen complexes containing a diphosphine ligand with a pendent amine

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Low Oxidation State Iron(0), Iron(I), and Ruthenium(0) Dinitrogen Complexes with a Very Bulky Neutral Phosphine Ligand

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, tau4

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Reversible carbon-carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Four-coordinate cobalt pincer complexes: electronic structure studies and ligand modification by homolytic and heterolytic pathways

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

7 January 2021

Cobalt PNC(NHC) 'pincers': ligand dearomatisation, formation of dinuclear and N2 complexes and promotion of C-H activation

1 reference

https://api.crossref.org/works/10.1002%2FEJIC.201700569

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