Radioactive silvery metal. Metal protected by oxide coating. Attached by steam and slowly by acids. Metal itself is soft an
ductile but alloys can be strong. Used in refractory materials, nuclear fuel elements, and incandescent gas mantles.
Diagnostic tests:
Thorium is usually detected by radioactivity (due, in part, to the
daughter elements such as radium). Uranium is also naturally radioactive;
however, many uranium minerals are generally yellow or green and
fluorescent, so if not, then suspect Th. Any radioactive mineral with a
negative reaction to uranium tests is probably thorium.
Thorium is usually associated with the rare earth
elements and use complicated schemes to identify the element. Basically,
the rare earths and thorium are precipitated as hydroxides from acid
solutions. The precipitate is dissolved in HCl and precipitated as
insoluble oxalates, washed, filtered and ignited to the oxides. The oxide
is dissolved in H2SO4 and ignited to dryness.
Dissolve the sulphates in water and precipitate Th using boiling sodium
thiosulfate solution. Repeat the thiosulfate step if necessary to
eliminate excess Ce, Zr, and Hf.
Infusible thorium minerals glow with exaggerated incandescence in the flame test
(along with Sr, Mg, Zr, Zn, Ca - the "lime light effect").
References
Emsley, J., 1991; THE ELEMENTS : Sec. Ed.,
Clarendon Press, Oxford, 251 p.
(* - Mineral Name Is Not IMA Approved)
(! - New Dana classification added or changed from Danas New Mineralogy)
(? - IMA Discredited Mineral Species Name)
There are 71 minerals with Th in the Mineralogy Database.