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Haber process

Artificial nitrogen fixation process which is the main industrial procedure for the production of ammonia nowadays

The Haber process or the Haber-Bosch process is a chemical reaction that uses nitrogen gas and hydrogen gas to create the chemical compound ammonia. The Haber process uses temperatures ranging from 400°C to 450°C under a pressure of 200 atm.[1] The Haber process uses a catalyst mostly made up of iron.

History

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The Haber process is named after the German scientist Fritz Haber. Haber was the first person to successfully complete the process. In 1909, Haber's process could produce about one cup of ammonia every two hours. Carl Bosch helped to develop the Haber process for industry. In 1913, the German company BASF started using the Haber process to make ammonia. During World War I, the Haber process was used to make explosives. The Germans kept this a secret until after the war. In 1918, Haber won the Nobel Prize in Chemistry, and in 1931, Bosch also shared a Nobel Prize.

The Haber process is still important today because it produces ammonia, which is needed for fertilizer and for many other purposes. The Haber process produces about 500 million tons (453 billion kilograms) of fertilizer every year. This fertilizer helps to feed about 40% of the world's population.[2]

Process

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The gases for the Haber process must be prepared before changing them into ammonia. After that is done, ammonia is created by using magnetite (iron oxide) as the catalyst:

N2 + 3H2 is in equilibrium with  2NH3

In this process, only about 15% of the nitrogen and hydrogen is changed into ammonia. However, the unused nitrogen and hydrogen is recycled. Overall, 98% of nitrogen and hydrogen can be changed into ammonia.

References

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  1. Jim Clark (2002), The Haber Process for the manufacture of ammonia, retrieved March 14, 2010
  2. What is the Haber-Bosch Process?, Wisegeek.com, retrieved March 14, 2010

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