(Q34082081)

30 July 2017

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title

Ynamides: a modern functional group for the new millennium (English)

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30 July 2017

Richard P Hsung

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30 July 2017

Kyle A DeKorver

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30 July 2017

Hongyan Li

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30 July 2017

Andrew G Lohse

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30 July 2017

Ryuji Hayashi

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30 July 2017

Zhenjie Lu

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30 July 2017

Yu Zhang

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30 July 2017

publication date

1 September 2010

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30 July 2017

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30 July 2017

volume

110

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30 July 2017

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30 July 2017

page(s)

5064-5106

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2+2 Cycloaddition of ketenes with ynamides. A general method for the synthesis of 3-aminocyclobutenone derivatives

30 July 2017

cites work

1 reference

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A unique approach to aldol products for the creation of all-carbon quaternary stereocentres

28 July 2018

1 reference

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SYNTHESIS OF YNAMIDES BY N-ALKYNYLATION OF AMINE DERIVATIVES. PREPARATION OF N-ALLYL-N-(METHOXYCARBONYL)-1,3-DECADIYNYLAMINE.

28 July 2018

1 reference

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A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Cu-catalyzed N-alkynylation of imidazoles, benzimidazoles, indazoles, and pyrazoles using PEG as solvent medium

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Preparation of multisubstituted enamides via rhodium-catalyzed carbozincation and hydrozincation of ynamides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Highly substituted 2-amido-furans from Rh(II)-catalyzed cyclopropenations of ynamides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

A highly stereoselective synthesis of chiral alpha-amino-beta-lactams via the Kinugasa reaction employing ynamides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Ruthenium-catalyzed azide-alkyne cycloaddition: scope and mechanism

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Synthesis of highly substituted indolines and indoles via intramolecular [4 + 2] cycloaddition of ynamides and conjugated enynes

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Copper-Mediated N-Alkynylation of Carbamates, Ureas, and Sulfonamides. A General Method for the Synthesis of Ynamides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

A copper-catalyzed C-N bond formation involving sp-hybridized carbons. A direct entry to chiral ynamides via N-alkynylation of amides

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

A Rhodium(I)-Xylyl-BINAP Catalyzed Asymmetric Ynamide-[2 + 2 + 2] Cycloaddition in the Synthesis of Optically Enriched N,O-Biaryls

28 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Nickel-catalyzed [3 + 2 + 2] cycloaddition of ethyl cyclopropylideneacetate and heteroatom-substituted alkynes: application to selective three-component reaction with 1,3-diynes.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Iron-catalyzed amidation of alkynyl bromides: a facile route for the preparation of ynamides.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

First total synthesis of antiostatin A1, a potent carbazole-based naturally occurring antioxidant

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Stereoselective synthesis of multisubstituted enamides via rhodium-catalyzed carbozincation of ynamides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Synthesis of tricyclic fused 3-aminopyridines through intramolecular Co(I)-catalyzed [2+2+2] cycloaddition between ynamides, nitriles, and alkynes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Synthesis of alpha-keto-imides via oxidation of ynamides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

A sequential metal-catalyzed C-N bond formation in the synthesis of 2-amido-indoles.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Gold-catalyzed synthesis of chroman, dihydrobenzofuran, dihydroindole, and tetrahydroquinoline derivatives

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Mechanistic studies on the Cu-catalyzed three-component reactions of sulfonyl azides, 1-alkynes and amines, alcohols, or water: dichotomy via a common pathway

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Copper-catalyzed 1,2-double amination of 1-halo-1-alkynes. Concise synthesis of protected tetrahydropyrazines and related heterocyclic compounds

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Copper-catalyzed highly efficient multicomponent reactions: synthesis of 2-(sulfonylimino)-4-(alkylimino)azetidine derivatives

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Rhodium(I)-catalyzed [2 + 2 + 2] cycloadditions of ynamides in the synthesis of amide-substituted chiral biaryls

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Enantioselective synthesis of axially chiral anilides through rhodium-catalyzed [2+2+2] cycloaddition of 1,6-diynes with trimethylsilylynamides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Theoretical analysis of the high versatility in PtCl2-mediated cycloisomerization of enynes on a common mechanistic basis

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

One-pot synthesis of metalated pyridines from two acetylenes, a nitrile, and a titanium(II) alkoxide

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Highly efficient one-pot synthesis of N-sulfonylamidines by Cu-catalyzed three-component coupling of sulfonyl azide, alkyne, and amine

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Copper sulfate-pentahydrate-1,10-phenanthroline catalyzed amidations of alkynyl bromides. Synthesis of heteroaromatic amine substituted ynamides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

Practical preparation of N-(1-Alkynyl)sulfonamides and their remote diastereoselective addition to aldehydes via titanation

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

A general and efficient copper catalyst for the amidation of aryl halides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

The first stereoselective Ficini-Claisen rearrangement using chiral ynamides

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2927719

28 October 2018

1 reference

12 December 2020

Palladium-Catalyzed cross-Benzannulation of Aminoenynes with Diynes. Highly Regioselective Synthesis of Polysubstituted Anilines

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12 December 2020

The synthesis and chemoselective reactivity of 3-aminocyclopentadienones

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12 December 2020

Low-energy pathway for pauson-khand reactions: synthesis and reactivity of dicobalt hexacarbonyl complexes of chiral ynamines

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12 December 2020

A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and theN-Arylation of Nitrogen Heterocycles

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12 December 2020

The Stille Reaction of 1,1-Dibromo-1-alkenes: Preparation of Trisubstituted Alkenes and Internal Alkynes

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12 December 2020

Stille cross-coupling reaction of an alpha-stannyl enamide

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12 December 2020

Synthesis of cyclic dienamide using ruthenium-catalyzed ring-closing metathesis of ene-ynamide

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12 December 2020

Synthesis and reactivity of an alpha-stannyl beta-silyl enamide

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12 December 2020

The first successful base-promoted isomerization of propargyl amides to chiral ynamides. Applications in ring-closing metathesis of ene-ynamides and tandem RCM of diene-ynamides

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12 December 2020

A highly efficient and flexible synthesis of substituted carbazoles by rhodium-catalyzed inter- and intramolecular alkyne cyclotrimerizations

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12 December 2020

Concise and stereoselective synthesis of enamides and dienamides by a titanium-mediated coupling method

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12 December 2020

Highly stereoselective synthesis of novel alpha-haloenamides via a mild and efficient hydrohalogenation of ynamides

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12 December 2020

Highly stereoselective Saucy-Marbet rearrangement using chiral ynamides. Synthesis of highly substituted chiral homoallenyl alcohols

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12 December 2020

Palladium‐Catalyzed Synthesis of 2‐Aminoindoles by a Heteroanulation Reaction

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12 December 2020

Radical cyclization cascade involving ynamides: an original access to nitrogen-containing heterocycles

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12 December 2020

Tandem enyne metathesis-Diels-Alder reaction for construction of natural product frameworks

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12 December 2020

Platinum dichloride-catalyzed cycloisomerization of ene-ynamides

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12 December 2020

Sonogashira cross-couplings of ynamides. Syntheses of urethane- and sulfonamide-terminated conjugated phenylacetylenic systems

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12 December 2020

Heck−Suzuki−Miyaura Domino Reactions Involving Ynamides. An Efficient Access to 3-(Arylmethylene)isoindolinones

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12 December 2020

An unexpected two-group migration involving a sulfonynamide to nitrile rearrangement. Mechanistic studies of a thermal N --> C tosyl rearrangement

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12 December 2020

Brønsted acid-catalyzed highly stereoselective arene-ynamide cyclizations. A novel keteniminium Pictet-Spengler cyclization in total syntheses of (+/-)-desbromoarborescidines A and C

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12 December 2020

Synthesis of carbazoles from ynamides by intramolecular dehydro Diels-Alder reactions

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12 December 2020

Ruthenium-catalyzed [2 + 2] cycloadditions of ynamides

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12 December 2020

Phosphine gold(I) bis-(trifluoromethanesulfonyl)imidate complexes as new highly efficient and air-stable catalysts for the cycloisomerization of enynes

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12 December 2020

Copper-catalyzed hydrative amide synthesis with terminal alkyne, sulfonyl azide, and water

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12 December 2020

A ring-closing yne-carbonyl metathesis of ynamides

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12 December 2020

Gold(I)-catalyzed formation of 4-alkylidene-1,3-dioxolan-2-ones from propargylic tert-butyl carbonates

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12 December 2020

A facile access to N-sulfonylimidates and their synthetic utility for the transformation to amidines and amides

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12 December 2020

Practical synthesis of amides from in situ generated copper(I) acetylides and sulfonyl azides

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12 December 2020

Copper-catalyzed reaction cascade: direct conversion of alkynes into N-sulfonylazetidin-2-imines

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12 December 2020

Copper(II)-catalyzed amidations of alkynyl bromides as a general synthesis of ynamides and Z-enamides. An intramolecular amidation for the synthesis of macrocyclic ynamides

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12 December 2020

Tandem azidination- and hydroazidination-Huisgen [3 + 2] cycloadditions of ynamides. Synthesis of chiral amide-substituted triazoles

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12 December 2020

Diastereoselective Gold-Catalyzed Cycloisomerizations of Ene-Ynamides

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12 December 2020

Novel and efficient synthesis of iminocoumarins via copper-catalyzed multicomponent reaction

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12 December 2020

A rhodium(I)-catalyzed demethylation-cyclization of o-anisole-substituted ynamides in the synthesis of chiral 2-amido benzofurans

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12 December 2020

Ruthenium-Catalyzed [2 + 2 + 2] Cocyclization of Diene-yne

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12 December 2020

Stereoselective Synthesis of 1,2-Aminoalcohols by [2,3]-Wittig Rearrangements

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12 December 2020

Direct synthesis of pyridine derivatives

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12 December 2020

Stereochemical control of both C-C and C-N axial chirality in the synthesis of chiral N,O-biaryls

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12 December 2020

A triazole-templated ring-closing metathesis for constructing novel fused and bridged triazoles

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12 December 2020

Synthesis and unusual reactivity of N-tosyl-4,5-benzoazacyclodeca-2,6-diyne, yneamino-containing enediyne

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12 December 2020

Copper-catalyzed multicomponent reaction: facile access to functionalized 5-arylidene-2-imino-3-pyrrolines

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12 December 2020

Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides

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12 December 2020

Reactive intermediates from DMDO oxidation of ynamides. Trapping of a de novo chiral push-pull carbene via cyclopropanation

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12 December 2020

Synthesis of functionalized oxazolones by a sequence of Cu(II)- and Au(I)-catalyzed transformations

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12 December 2020

Copper-catalyzed multicomponent reaction: facile access to novel phosphorus amidines

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12 December 2020

Palladium-catalyzed intermolecular ene-yne coupling: development of an atom-efficient Mizoroki-Heck-type reaction

1 reference

12 December 2020

Mo-Au combo catalysis for rapid 1,3-rearrangement of propargyl alcohols into alpha,beta-unsaturated carbonyl compounds

1 reference

12 December 2020

Coupling reactions of bromoalkynes with imidazoles mediated by copper salts: synthesis of novel N-alkynylimidazoles

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12 December 2020

Nickel-Catalyzed Highly Regioselective Multicomponent Coupling of Ynamides, Aldehydes, and Silane: A New Access to Functionalized Enamides

1 reference

12 December 2020

Ruthenium-catalyzed cycloaddition of nitrile oxides and alkynes: practical synthesis of isoxazoles

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12 December 2020

Diversity in gold- and silver-catalyzed cycloisomerization of epoxide-alkyne functionalities

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12 December 2020

Irregularities in the Effect of Potassium Phosphate in Ynamide Synthesis

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12 December 2020

Application of ynamides in the synthesis of 2-amidoindoles

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12 December 2020

Copper-mediated coupling of 1,1-dibromo-1-alkenes with nitrogen nucleophiles: a general method for the synthesis of ynamides

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12 December 2020

Atropisomerism of alpha,beta-unsaturated amidines: stereoselective synthesis by catalytic cascade reaction and optical resolution

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12 December 2020

Ruthenium-catalyzed [2 + 2] cycloadditions of bicyclic alkenes with alkynyl phosphonates

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12 December 2020

Highly regioselective Au(I)-catalyzed hydroamination of ynamides and propiolic acid derivatives with anilines

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12 December 2020

Creating aldols differently: how to build up aldol products with quaternary stereocenters starting from alkynes

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12 December 2020

Synthesis of ketene N,N-acetals by copper-catalyzed double-amidation of 1,1-dibromo-1-alkenes

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12 December 2020

Synthesis and molecular properties of donor-pi-spacer-acceptor ynamides with up to four conjugated alkyne units

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12 December 2020

N-Functionalized 1-Alkynylamides: New Building Blocks for Transition Metal Mediated Inter- and Intramolecular [2+2+1] Cycloadditions

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12 December 2020

Identifiers

DOI

10.1021/CR100003S

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30 July 2017

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30 July 2017

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