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Electronvolt

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In physics, an electronvolt (symbol eV), also written electron-volt and electron volt, is the measure of an amount of kinetic energy gained by a single electron accelerating through an electric potential difference of one volt in vacuum. When used as a unit of energy, the numerical value of 1 eV in joules (symbol J) is equal to the numerical value of the charge of an electron in coulombs (symbol C). Under the 2019 revision of the SI, this sets 1 eV equal to the exact value 1.602176634×10−19 J.[1]

electronvolt
Unit systemNon-SI accepted unit
Unit ofenergy
SymboleV
Conversions
1 eV in ...... is equal to ...
   joules (SI)   1.602176634×10−19 J.[1]

Historically, the electronvolt was devised as a standard unit of measure through its usefulness in electrostatic particle accelerator sciences, because a particle with electric charge q gains an energy E = qV after passing through a voltage of V.

Definition and use

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An electronvolt is the amount of energy gained or lost by a single electron when it moves through an electric potential difference of one volt. Hence, it has a value of one volt, which is 1 J/C, multiplied by the elementary charge e = 1.602176634×10−19 C.[2] Therefore, one electronvolt is equal to 1.602176634×10−19 J.[1]

The electronvolt (eV) is a unit of energy, but is not an SI unit. It is a commonly used unit of energy within physics, widely used in solid state, atomic, nuclear and particle physics, and high-energy astrophysics. It is commonly used with SI prefixes milli- (10-3), kilo- (103), mega- (106), giga- (109), tera- (1012), peta- (1015) or exa- (1018), the respective symbols being meV, keV, MeV, GeV, TeV, PeV and EeV. The SI unit of energy is the joule (J).

In some older documents, and in the name Bevatron, the symbol BeV is used, where the B stands for billion. The symbol BeV is therefore equivalent to GeV, though neither is an SI unit.

Relation to other physical properties and units

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Quantity Unit SI value of unit
energy eV 1.602176634×10−19 J[1]
mass eV/c2 1.78266192×10−36 kg
momentum eV/c 5.34428599×10−28 kg·m/s
temperature eV/kB 11604.51812 K
time ħ/eV 6.582119×10−16 s
distance ħc/eV 1.97327×10−7 m

In the fields of physics in which the electronvolt is used, other quantities are typically measured using units derived from the electronvolt as a product with fundamental constants of importance in the theory are often used.

Mass

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By mass–energy equivalence, the electronvolt corresponds to a unit of mass. It is common in particle physics, where units of mass and energy are often interchanged, to express mass in units of eV/c2, where c is the speed of light in vacuum (from E = mc2). It is common to informally express mass in terms of eV as a unit of mass, effectively using a system of natural units with c set to 1.[3] The kilogram equivalent of 1 eV/c2 is:

 

For example, an electron and a positron, each with a mass of 0.511 MeV/c2, can annihilate to yield 1.022 MeV of energy. A proton has a mass of 0.938 GeV/c2. In general, the masses of all hadrons are of the order of 1 GeV/c2, which makes the GeV/c2 a convenient unit of mass for particle physics:[4]

1 GeV/c2 = 1.78266192×10−27 kg.

The atomic mass constant (mu), one twelfth of the mass a carbon-12 atom, is close to the mass of a proton. To convert to electronvolt mass-equivalent, use the formula:

mu = 1 Da = 931.4941 MeV/c2 = 0.9314941 GeV/c2.

Momentum

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By dividing a particle's kinetic energy in electronvolts by the fundamental constant c (the speed of light), one can describe the particle's momentum in units of eV/c.[5] In natural units in which the fundamental velocity constant c is numerically 1, the c may be informally be omitted to express momentum using the unit electronvolt.

 
The energy–momentum relation in natural units,  , is a Pythagorean equation that can be visualized as a right triangle where the total energy   is the hypotenuse and the momentum   and rest mass   are the two legs.

The energy–momentum relation   in natural units (with  )   is a Pythagorean equation. When a relatively high energy is applied to a particle with relatively low rest mass, it can be approximated as   in high-energy physics such that an applied energy with expressed in the unit eV conveniently results in a numerically approximately equivalent change of momentum when expressed with the unit eV/c.

The dimension of momentum is T−1LM. The dimension of energy is T−2L2M. Dividing a unit of energy (such as eV) by a fundamental constant (such as the speed of light) that has the dimension of velocity (T−1L) facilitates the required conversion for using a unit of energy to quantify momentum.

For example, if the momentum p of an electron is 1 GeV/c, then the conversion to MKS system of units can be achieved by:  

Distance

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In particle physics, a system of natural units in which the speed of light in vacuum c and the reduced Planck constant ħ are dimensionless and equal to unity is widely used: c = ħ = 1. In these units, both distances and times are expressed in inverse energy units (while energy and mass are expressed in the same units, see mass–energy equivalence). In particular, particle scattering lengths are often presented using a unit of inverse particle mass.

Outside this system of units, the conversion factors between electronvolt, second, and nanometer are the following:  

The above relations also allow expressing the mean lifetime τ of an unstable particle (in seconds) in terms of its decay width Γ (in eV) via Γ = ħ/τ. For example, the
B0
meson
has a lifetime of 1.530(9) picoseconds, mean decay length is = 459.7 μm, or a decay width of 4.302(25)×10−4 eV.

Conversely, the tiny meson mass differences responsible for meson oscillations are often expressed in the more convenient inverse picoseconds.

Energy in electronvolts is sometimes expressed through the wavelength of light with photons of the same energy:  

Temperature

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In certain fields, such as plasma physics, it is convenient to use the electronvolt to express temperature. The electronvolt is divided by the Boltzmann constant to convert to the Kelvin scale:   where kB is the Boltzmann constant.

The kB is assumed when using the electronvolt to express temperature, for example, a typical magnetic confinement fusion plasma is 15 keV (kiloelectronvolt), which is equal to 174 MK (megakelvin).

As an approximation: kBT is about 0.025 eV (≈ 290 K/11604 K/eV) at a temperature of 20 °C.

Wavelength

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Energy of photons in the visible spectrum in eV
 
Graph of wavelength (nm) to energy (eV)

The energy E, frequency ν, and wavelength λ of a photon are related by   where h is the Planck constant, c is the speed of light. This reduces to[6]   A photon with a wavelength of 532 nm (green light) would have an energy of approximately 2.33 eV. Similarly, 1 eV would correspond to an infrared photon of wavelength 1240 nm or frequency 241.8 THz.

Scattering experiments

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In a low-energy nuclear scattering experiment, it is conventional to refer to the nuclear recoil energy in units of eVr, keVr, etc. This distinguishes the nuclear recoil energy from the "electron equivalent" recoil energy (eVee, keVee, etc.) measured by scintillation light. For example, the yield of a phototube is measured in phe/keVee (photoelectrons per keV electron-equivalent energy). The relationship between eV, eVr, and eVee depends on the medium the scattering takes place in, and must be established empirically for each material.

Energy comparisons

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Photon frequency vs. energy particle in electronvolts. The energy of a photon varies only with the frequency of the photon, related by the speed of light. This contrasts with a massive particle of which the energy depends on its velocity and rest mass.[7][8][9]
Legend
γ: gamma rays MIR: mid-infrared HF: high freq.
HX: hard X-rays FIR: far infrared MF: medium freq.
SX: soft X-rays radio waves LF: low freq.
EUV: extreme ultraviolet EHF: extremely high freq. VLF: very low freq.
NUV: near ultraviolet SHF: super high freq. ULF: ultra-low freq.
visible light UHF: ultra high freq. SLF: super low freq.
NIR: near infrared VHF: very high freq. ELF: extremely low freq.
Energy Source
3×1058 QeV mass-energy of all ordinary matter in the observable universe[10]
52.5 QeV energy released from a 20 kiloton of TNT equivalent explosion (e.g. the nuclear weapon yield of the Fat Man fission bomb)
12.2 ReV the Planck energy
10 YeV approximate grand unification energy
300 EeV first ultra-high-energy cosmic ray particle observed, the so-called Oh-My-God particle[11]
62.4 EeV energy consumed by a 10-watt device (e.g. a typical[12] LED light bulb) in one second (10 W = 10 J/s6.24×1019 eV/s)
PeV the highest-energy neutrino detected by the IceCube neutrino telescope in Antarctica[13]
14 TeV designed proton center-of-mass collision energy at the Large Hadron Collider (operated at 3.5 TeV since its start on 30 March 2010, reached 13 TeV in May 2015)
1 TeV 0.1602 μJ, about the kinetic energy of a flying mosquito[14]
172 GeV rest mass energy of the top quark, the heaviest elementary particle for which this has been determined
125.1±0.2 GeV rest mass energy of the Higgs boson, as measured by two separate detectors at the LHC to a certainty better than 5 sigma[15]
210 MeV average energy released in fission of one Pu-239 atom
200 MeV approximate average energy released in nuclear fission of one U-235 atom.
105.7 MeV rest mass energy of a muon
17.6 MeV average energy released in the nuclear fusion of deuterium and tritium to form He-4; this is 0.41 PJ per kilogram of product produced
2 MeV approximate average energy released in a nuclear fission neutron released from one U-235 atom.
1.9 MeV rest mass energy of up quark, the lowest-mass quark.
1 MeV 0.1602 pJ, about twice the rest mass energy of an electron
1 to 10 keV approximate thermal energy, kBT, in nuclear fusion systems, like the core of the sun, magnetically confined plasma, inertial confinement and nuclear weapons
13.6 eV the energy required to ionize atomic hydrogen; molecular bond energies are on the order of 1 eV to 10 eV per bond
1.65 to 3.26 eV range of photon energy   of visible spectrum from red to violet
1.1 eV energy   required to break a covalent bond in silicon
720 meV energy   required to break a covalent bond in germanium
120 meV upper bound on the rest mass energy of neutrinos (sum of 3 flavors)[16]
38 meV average kinetic energy, 3/2kBT, of one gas molecule at room temperature
25 meV thermal energy, kBT, at room temperature
230 μeV thermal energy, kBT, at the cosmic microwave background radiation temperature of ~2.7 kelvin

Molar energy

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One mole of particles given 1 eV of energy each has approximately 96.5 kJ of energy – this corresponds to the Faraday constant (F96485 C⋅mol−1), where the energy in joules of n moles of particles each with energy E eV is equal to E·F·n.

See also

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References

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  1. ^ a b c d "2022 CODATA Value: electron volt". The NIST Reference on Constants, Units, and Uncertainty. NIST. May 2024. Retrieved 2024-05-18.
  2. ^ "2022 CODATA Value: elementary charge". The NIST Reference on Constants, Units, and Uncertainty. NIST. May 2024. Retrieved 2024-05-18.
  3. ^ Barrow, J. D. (1983). "Natural Units Before Planck". Quarterly Journal of the Royal Astronomical Society. 24: 24. Bibcode:1983QJRAS..24...24B.
  4. ^ Gron Tudor Jones. "Energy and momentum units in particle physics" (PDF). Indico.cern.ch. Retrieved 5 June 2022.
  5. ^ "Units in particle physics". Associate Teacher Institute Toolkit. Fermilab. 22 March 2002. Archived from the original on 14 May 2011. Retrieved 13 February 2011.
  6. ^ "2022 CODATA Value: Planck constant in eV/Hz". The NIST Reference on Constants, Units, and Uncertainty. NIST. May 2024. Retrieved 2024-05-18.
  7. ^ Molinaro, Marco (9 January 2006). ""What is Light?"" (PDF). University of California, Davis. IST 8A (Shedding Light on Life) - W06. Archived from the original (PDF) on 29 November 2007. Retrieved 7 February 2014.
  8. ^ Elert, Glenn. "Electromagnetic Spectrum, The Physics Hypertextbook". hypertextbook.com. Archived from the original on 2016-07-29. Retrieved 2016-07-30.
  9. ^ "Definition of frequency bands on". Vlf.it. Archived from the original on 2010-04-30. Retrieved 2010-10-16.
  10. ^ Lochner, Jim (11 February 1998). "Big Bang Energy". NASA. Help from: Kowitt, Mark; Corcoran, Mike; Garcia, Leonard. Archived from the original on 19 August 2014. Retrieved 26 December 2016.
  11. ^ Baez, John (July 2012). "Open Questions in Physics". DESY. Archived from the original on 11 March 2020. Retrieved 19 July 2012.
  12. ^ "How Many Watts Does a Light Bulb Use?". EnergySage. Retrieved 2024-06-06.
  13. ^ "A growing astrophysical neutrino signal in IceCube now features a 2-PeV neutrino". 21 May 2014. Archived from the original on 2015-03-19.
  14. ^ "Glossary". Compact Muon Solenoid. CERN. Electronvolt (eV). Archived from the original on 11 December 2013. Retrieved 18 August 2014.
  15. ^ ATLAS; CMS (26 March 2015). "Combined Measurement of the Higgs Boson Mass in pp Collisions at √s=7 and 8 TeV with the ATLAS and CMS Experiments". Physical Review Letters. 114 (19): 191803. arXiv:1503.07589. Bibcode:2015PhRvL.114s1803A. doi:10.1103/PhysRevLett.114.191803. PMID 26024162.
  16. ^ Mertens, Susanne (2016). "Direct neutrino mass experiments". Journal of Physics: Conference Series. 718 (2): 022013. arXiv:1605.01579. Bibcode:2016JPhCS.718b2013M. doi:10.1088/1742-6596/718/2/022013. S2CID 56355240.
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