Potassium bisulfite

Potassium bisulfite
Names
	IUPAC name Potassium hydrogen sulfite
	Other names Potassium bisulfite; potassium bisulphite; monopotassium salt; monopotassium sulfite; potassium hydrosulfite;
Identifiers
CAS Number	7773-03-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	22889 ;
ECHA InfoCard	100.028.973
EC Number	231-870-1;
E number	E228 (preservatives)
PubChem CID	23663620;
UNII	QJK5LO891P ;
CompTox Dashboard (EPA)	DTXSID6064795 ;
	InChI InChI=1S/K.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1;
	SMILES OS(=O)[O-].[K+];
Properties
Chemical formula	KHSO3
Molar mass	120.1561 g/mol
Appearance	White crystalline powder
Odor	SO2-like
Melting point	190 °C (374 °F; 463 K) (decomposes)
Solubility in water	49 g/100 mL (20 °C) ; 115 g/100 mL (100 °C)
Solubility	Insoluble in alcohol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Potassium bisulfite (or potassium hydrogen sulfite) is a chemical mixture with the approximately correctly mentioned formula chemical formula KHSO₃. Potassium bisulfite in fact is not a actual compound,^[1] but a mixture of salts that dissolve in water to give solutions composed of potassium ions and bisulfite ions. It is a white solid with an odor of sulfur dioxide. Attempts to crystallize potassium bisulfite yield potassium metabisulfite, K₂S₂O₅.^[2]

Potassium bisulfite is used as a sterilising agent in the production of alcoholic beverages.^[3] This additive is classified as E number E228 under the current EU-approved food additive legislation.^[4]

Production

It is made by the reaction of sulfur dioxide and potassium carbonate. The sulfur dioxide is passed through a solution of the potassium carbonate until no more carbon dioxide is evolved. The solution is concentrated.

References

^ Tudela, David; Jenkins, H. Donald B. (2003). "New Methods to Estimate Lattice Energies: Application to the Relative Stabilities of Bisulfite (HSO₃⁻) and Metabisulfite (S₂O₅^2-) Salts". Journal of Chemical Education. 80 (12): 1482. Bibcode:2003JChEd..80.1482T. doi:10.1021/ed080p1482.
^ Johnstone, H. F. (1946). "Sulfites and Pyrosulfites of the Alkali Metals". Inorganic Syntheses. Vol. 2. pp. 162–167. doi:10.1002/9780470132333.ch49. ISBN 9780470132333.
^ Barberá, José Jiménez; Metzger, Adolf; Wolf, Manfred (2000). "Sulfites, Thiosulfates, and Dithionitesl Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a25_477. ISBN 3527306730.
^ "Approved additives and E numbers". Food Standards Agency. Retrieved 2020-04-07.

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[1] Tudela, David; Jenkins, H. Donald B. (2003). "New Methods to Estimate Lattice Energies: Application to the Relative Stabilities of Bisulfite (HSO₃⁻) and Metabisulfite (S₂O₅^2-) Salts". Journal of Chemical Education. 80 (12): 1482. Bibcode:2003JChEd..80.1482T. doi:10.1021/ed080p1482.

[2] Johnstone, H. F. (1946). "Sulfites and Pyrosulfites of the Alkali Metals". Inorganic Syntheses. Vol. 2. pp. 162–167. doi:10.1002/9780470132333.ch49. ISBN 9780470132333.

[3] Barberá, José Jiménez; Metzger, Adolf; Wolf, Manfred (2000). "Sulfites, Thiosulfates, and Dithionitesl Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a25_477. ISBN 3527306730.

[4] "Approved additives and E numbers". Food Standards Agency. Retrieved 2020-04-07.

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Names


IUPAC name Potassium hydrogen sulfite
Other names Potassium bisulfite potassium bisulphite monopotassium salt monopotassium sulfite potassium hydrosulfite
Identifiers
CAS Number	7773-03-7^Y
3D model (JSmol)	Interactive image
ChemSpider	22889^N
ECHA InfoCard	100.028.973
EC Number	231-870-1
E number	E228 (preservatives)
PubChem CID	23663620
UNII	QJK5LO891P^N
CompTox Dashboard (EPA)	DTXSID6064795
InChI InChI=1S/K.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1
SMILES OS(=O)[O-].[K+]
Properties
Chemical formula	KHSO₃
Molar mass	120.1561 g/mol
Appearance	White crystalline powder
Odor	SO₂-like
Melting point	190 °C (374 °F; 463 K) (decomposes)
Solubility in water	49 g/100 mL (20 °C) 115 g/100 mL (100 °C)
Solubility	Insoluble in alcohol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references

Potassium bisulfite

Production

See also

References