Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules (Q35758570)

10 August 2017

title

Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules (English)

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10 August 2017

main subject

coordination chemistry

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Gregory J Kubas

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10 August 2017

language of work or name

English

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publication date

18 April 2007

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Proceedings of the National Academy of Sciences of the United States of America

10 August 2017

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inferred from page(s)

published in

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10 August 2017

volume

104

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10 August 2017

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10 August 2017

page(s)

6901-6907

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A mercury-catalyzed, high-yield system for the oxidation of methane to methanol

10 August 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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2 October 2017

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A neutron diffraction study of [OsClH3(PPh3)3]: a complex containing a highly "stretched" dihydrogen ligand

2 October 2017

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25 September 2018

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Synthesis, neutron structure, and reactivity of the bis(dihydrogen) complex RuH2(eta(2)-H2)2(PCyp3)2 stabilized by two tricyclopentylphosphines.

25 September 2018

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Characterization of H2Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering

25 September 2018

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25 September 2018

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25 September 2018

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25 September 2018

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25 September 2018

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25 September 2018

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25 September 2018

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Theoretical Studies of Some Transition-Metal-Mediated Reactions of Industrial and Synthetic Importance

25 September 2018

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Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

25 September 2018

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Photochemistry of the Group 6 hexacarbonyls in low-temperature matrices. III. Interaction of the pentacarbonyls with noble gases and other matrices

21 January 2018

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Photolysis of hexacarbonylchromium in hydrogen-containing matrixes: evidence of simple adducts of molecular hydrogen

21 January 2018

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Comparative bonding study of conical fragments

21 January 2018

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Electronic stability of metal-dihydrogen and polyhydrogen complexes

21 January 2018

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Transition Metal Polyhydrides: From Qualitative Ideas to Reliable Computational Studies†

21 January 2018

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Neutron structure and inelastic-neutron-scattering and theoretical studies of molybdenum complex Mo(CO)(H2)[(C6D5)2PC2H4P(C6D5)2]2.cntdot.4.5C6D6, a complex with an extremely low barrier to hydrogen rotation. Implications on the reaction coordinate f

21 January 2018

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Structure and H2-Loss Energies of OsHX(H2)(CO)L2Complexes (L = P(t-Bu)2Me, P(i-Pr)3; X = Cl, I, H): Attempted Correlation of1J(H−D),T1min, and ΔG⧧

21 January 2018

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OsH5(PMe2Ph)3+: Structure, Reactivity, and Its Use as a Catalyst Precursor for Olefin Hydrogenation and Hydroformylation

21 January 2018

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Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes

21 January 2018

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Deprotonation of uncharged transition-metal dihydrogen complexes with copper alkoxides, characterization of the heterometallic complexes (PR3)xMHyCu(PR3) (M = iron, tungsten), and x-ray crystal structure of (PEtPh2)3FeH3Cu(PEtPh2)

21 January 2018

1 reference

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An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3

21 January 2018

1 reference

https://api.crossref.org/works/10.1073%2FPNAS.0609707104

Determination of the Structure of [Os(.eta.2-H2)en2CH3CO2]PF6 by X-ray and Neutron Diffraction

21 January 2018

1 reference

https://api.crossref.org/works/10.1073%2FPNAS.0609707104

The sigma-CAM Mechanism: sigma complexes as the basis of sigma-bond metathesis at late-transition-metal centers.

21 January 2018

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12 December 2020

Synthesis and spectroscopic properties of elongated ruthenium dihydrogen complexes: temperature and isotope dependence of H-H distances

1 reference

12 December 2020

Adsorption of molecular hydrogen on coordinatively unsaturated Ni(II) sites in a nanoporous hybrid material

1 reference

12 December 2020

Quantum Mechanical Exchange Coupling in Polyhydride and Dihydrogen Complexes

1 reference

12 December 2020

Structural and bonding characteristics in transition metal–silane complexes

1 reference

12 December 2020

Ruthenium-catalyzed ionic hydrogenation of iminium cations. Scope and mechanism

1 reference

12 December 2020

Evidence for chemisorbed molecular hydrogen in Fe-ZSM5 from inelastic neutron scattering

1 reference

12 December 2020

Molybdenocene trihydride complexes: influence of a [Me2Si] ansa bridge on classical versus nonclassical nature, stability with respect to elimination of dihydrogen, and acidity

1 reference

12 December 2020

Determination of the temperature dependence of the H-D spin-spin coupling constant and the isotope effect on the proton chemical shift for the compressed dihydride complex [CpIr(P-P)H2]2+

1 reference

12 December 2020

Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of Osmium and Ruthenium

1 reference

12 December 2020

Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction

1 reference

12 December 2020

How Many Hydrogen Atoms Can Be Bound to a Metal? Predicted MH12Species

1 reference

12 December 2020

Effect of weak interactions on the H...H distance in stretched dihydrogen complexes

1 reference

12 December 2020

Water splitting goes au naturel

1 reference

12 December 2020

Elongated dihydrogen versus compressed dihydride complexes: the temperature dependence of the H-D spin-spin coupling constant as a criterion to distinguish between them

1 reference

12 December 2020

Bridging the Gap between Homogeneous and Heterogeneous Catalysis: Ortho/Para H2Conversion, Hydrogen Isotope Scrambling, and Hydrogenation of Olefins by Ir(CO)Cl(PPh3)2

1 reference

12 December 2020

Observation of molecular H2 chemisorption on a nickel surface

1 reference

12 December 2020

Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds

1 reference

12 December 2020

Kubas complexes revisited: novel dihydride complexes of tungsten

1 reference

12 December 2020

Dihydrogen activation by a diruthenium analogue of the Fe-only hydrogenase active site

1 reference

12 December 2020

Proton‐Induced Change of the Coordination Mode of a Boron Group: Boryl Complexes [Mn(CO)4(PR3)(BH2⋅PMe3)] and Cationic Borane σ Complexes [Mn(CO)4(PR3)(η1‐BH3⋅PMe3)]+

1 reference

12 December 2020

Dihydrogen Complexes as Homogeneous Reduction Catalysts

1 reference

12 December 2020

Transition Metal Alkane Complexes(dagger)

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12 December 2020

Identifiers

DOI

10.1073/PNAS.0609707104

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10 August 2017

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10 August 2017

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