A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site (Q35147804)

6 August 2017

title

A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site (English)

1 reference

6 August 2017

Matthew A Cranswick

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Yisong Guo

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Jason England

1 reference

6 August 2017

Katherine M Van Heuvelen

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6 August 2017

Gregory T Rohde

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6 August 2017

Emile L Bominaar

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6 August 2017

Eckard Münck

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6 August 2017

Lawrence Que

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6 August 2017

language of work or name

English

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publication date

19 July 2011

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Journal of the American Chemical Society

6 August 2017

published in

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6 August 2017

volume

133

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6 August 2017

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6 August 2017

page(s)

11880-11883

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Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity

6 August 2017

cites work

1 reference

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Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex.

13 July 2018

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The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway

13 July 2018

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Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage

13 July 2018

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The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes

13 July 2018

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Substrate positioning controls the partition between halogenation and hydroxylation in the aliphatic halogenase, SyrB2.

13 July 2018

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First-principles study of non-heme Fe(II) halogenase SyrB2 reactivity

13 July 2018

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A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity

13 July 2018

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Substrate-triggered formation and remarkable stability of the C-H bond-cleaving chloroferryl intermediate in the aliphatic halogenase, SyrB2

13 July 2018

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Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes

13 July 2018

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Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate

13 July 2018

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13 July 2018

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Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity

13 July 2018

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Direct spectroscopic evidence for a high-spin Fe(IV) intermediate in tyrosine hydroxylase

13 July 2018

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The road to non-heme oxoferryls and beyond

13 July 2018

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13 July 2018

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Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase

13 July 2018

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Mechanism of selective halogenation by SyrB2: a computational study.

13 July 2018

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Carbon dioxide: a waste product in the catalytic cycle of alpha-ketoglutarate dependent halogenases prevents the formation of hydroxylated by-products

27 September 2018

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Spectroscopic evidence for a high-spin Br-Fe(IV)-oxo intermediate in the alpha-ketoglutarate-dependent halogenase CytC3 from Streptomyces

27 September 2018

1 reference

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Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: alpha-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant.

27 September 2018

1 reference

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EXAFS spectroscopic evidence for an Fe=O unit in the Fe(IV) intermediate observed during oxygen activation by taurine:alpha-ketoglutarate dioxygenase

27 September 2018

1 reference

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Direct detection of oxygen intermediates in the non-heme Fe enzyme taurine/alpha-ketoglutarate dioxygenase.

27 September 2018

1 reference

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The first direct characterization of a high-valent iron intermediate in the reaction of an alpha-ketoglutarate-dependent dioxygenase: a high-spin FeIV complex in taurine/alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli

27 September 2018

1 reference

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Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations

27 September 2018

1 reference

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Quantum chemical studies of C–H activation reactions by high-valent nonheme iron centers

16 November 2018

1 reference

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Electronic structure and spectroscopy of “superoxidized” iron centers in model systems: theoretical and experimental trends

16 November 2018

1 reference

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Two interconverting Fe(IV) intermediates in aliphatic chlorination by the halogenase CytC3

16 November 2018

1 reference

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Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

16 November 2018

1 reference

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Aqueous FeIV==O: spectroscopic identification and oxo-group exchange

16 November 2018

1 reference

12 December 2020

Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy

1 reference

12 December 2020

Why does the enzyme SyrB2 chlorinate, but does not hydroxylate, saturated hydrocarbons? A density functional theory (DFT) study

1 reference

12 December 2020

Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA2040909

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6 August 2017

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6 August 2017

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