Copper-Catalysed, Enantioselective Desymmetrisation ofmeso Cyclic Allylic Bis(diethyl phosphates) with Organozinc Reagents (Q57973383)

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Language	Label	Description	Also known as
English	Copper-Catalysed, Enantioselective Desymmetrisation ofmeso Cyclic Allylic Bis(diethyl phosphates) with Organozinc Reagents	No description defined

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scholarly article

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Copper-Catalysed, Enantioselective Desymmetrisation ofmeso Cyclic Allylic Bis(diethyl phosphates) with Organozinc Reagents (English)

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enantioselectivity

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inferred from title

5

object named as

Cesare Gennari

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Umberto Piarulli

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object named as

Umberto Piarulli

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author name string

Philippe Daubos

2

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Christelle Claverie

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Chiara Monti

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publication date

March 2005

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European Journal of Organic Chemistry

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2005

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5

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895-906

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Experimental evidence supporting a CuIII intermediate in cross-coupling reactions of allylic esters with diallylcuprate species

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Copper(I)-Catalyzed Enantioselective Substitution of Allyl Chlorides with Diorganozinc Compounds

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Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper-Catalyzed Allylic Substitutions

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Cu-catalyzed asymmetric allylic alkylations of aromatic and aliphatic phosphates with alkylzinc reagents. An effective method for enantioselective synthesis of tertiary and quaternary carbons

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Enantioselective copper-catalyzed allylic alkylation with dialkylzincs using phosphoramidite ligands

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Synthesis and Screening of New Chiral Ligands for the Copper-Catalysed Enantioselective Allylic Substitution

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Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex

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Tandem copper-catalyzed enantioselective allylation-metathesis

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A highly effective phosphoramidite ligand for asymmetric allylic substitution

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Enantioselective desymmetrisation

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Pd-catalyzed enantioselective allylic substitution: new strategic options for the total synthesis of natural products

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Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis

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Enantioselective Ring Opening of Aza and Oxabicyclic Alkenes with Dimethylzinc.

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Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids

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Copper phosphoramidite catalyzed enantioselective ring-opening of oxabicyclic alkenes: remarkable reversal of stereocontrol.

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A Catalytic and Enantioselective Desymmetrization of meso Cyclic Allylic Bisdiethylphosphates with Organozinc Reagents

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Copper Phosphoramidite-Catalyzed Enantioselective Desymmetrization ofmeso-Cyclic Allylic Bisdiethyl Phosphates

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Discovery of a New Efficient Chiral Ligand for Copper-Catalyzed Enantioselective Michael Additions by High-Throughput Screening of a Parallel Library

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Optimization of New Chiral Ligands for the Copper-Catalysed Enantioselective Conjugate Addition of Et2Zn to Nitroolefins by High-Throughput Screening of a Parallel Library

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Discovery of a new efficient chiral ligand for copper-catalyzed enantioselective Michael additions by high-throughput screening of a parallel library.

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Scope and limitation of organocuprates, and copper or nickel catalyst-modified Grignard reagents for installation of an alkyl group onto cis-4-cyclopentene-1,3-diol monoacetate.

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Copper catalysed 1,4-addition of organozinc reagents to α,β-unsaturated carbonyl compounds: a mechanistic investigation

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Nonlinear Effects in Asymmetric Synthesis and Stereoselective Reactions: Ten Years of Investigation

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Asymmetric, Catalytic Phenyl Transfer to Aldehydes: Enantioselective Synthesis of Diarylmethanols

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New Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR2to Carbonyl Compounds

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Highly enantioselective Cu-catalysed asymmetric 1,4-addition of diphenylzinc to cyclohexenone

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Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters

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Correlation of configuration and fluorine-19 chemical shifts of .alpha.-methoxy-.alpha.-trifluoromethylphenyl acetate derivatives

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Phosphoramidites: marvellous ligands in catalytic asymmetric conjugate addition

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Regio- and enantioselective iridium-catalyzed allylic alkylation with in situ activated P,C-chelate complexes

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Enantioselective Conjugate Addition of Dialkylzinc Reagents to Cyclic and Acyclic Enones Catalyzed by Chiral Copper Complexes of New Phosphorus Amidites

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Highly Enantioselective Catalytic Conjugate Addition and Tandem Conjugate Addition–Aldol Reactions of Organozinc Reagents

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Asymmetric Conjugate Addition Reactions of Meldrum's Acid Derived Acceptors Employing Chiral Phosphoramidite Ligands

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Highly enantioselective conjugate addition of dialkylzinc reagents to acyclic nitroalkenes: a catalytic route to beta2-amino acids, aldehydes, and alcohols

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Highly Enantioselective Regiodivergent and Catalytic Parallel Kinetic Resolution This work was supported by the Ministero dell'Università e della Ricerca Scientifica e Tecnologica (MURST, Roma) and by the University of Pisa. We gratefully acknowledg

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Catalytic regiodivergent kinetic resolution of allylic epoxides: a new entry to allylic and homoallylic alcohols with high optical purity

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A new catalytic and enantioselective desymmetrization of symmetrical methylidene cycloalkene oxides

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High efficiency and enantioselectivity in the rh-catalyzed conjugate addition of arylboronic acids using monodentate phosphoramidites

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First examples of improved catalytic asymmetric C-C bond formation using the monodentate ligand combination approach

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10.1002/EJOC.200400757

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